Tri(2-furyl)phosphine

Product Information

Molecular Formula:
C12H9O3P
Molecular Weight:
232.17
Description
Tri(2-furyl)phosphine (CAS# 5518-52-5) is a useful research chemical.
Synonyms
tris(2-furanyl)phosphine; tris(furan-2-yl)phosphane
IUPAC Name
tris(furan-2-yl)phosphane
Canonical SMILES
C1=COC(=C1)P(C2=CC=CO2)C3=CC=CO3
InChI
InChI=1S/C12H9O3P/c1-4-10(13-7-1)16(11-5-2-8-14-11)12-6-3-9-15-12/h1-9H
InChI Key
DLQYXUGCCKQSRJ-UHFFFAOYSA-N
Boiling Point
136 °C / 4 mmHg (lit.)
Melting Point
59-64 °C (lit.)
Flash Point
Not applicable
Purity
99 %
LogP
2.22380

Safety Information

Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning

Computed Properties

XLogP3
2.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
3
Exact Mass
232.02893114 g/mol
Monoisotopic Mass
232.02893114 g/mol
Topological Polar Surface Area
39.4Ų
Heavy Atom Count
16
Formal Charge
0
Complexity
198
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114015021-A Terminal functional side chain substituted pyrrolopyrroledione-based terpolymer and preparation method and application thereof 2021-10-28
CN-113817157-A Semi-aromatic polyamide polycondensation catalyst and preparation method thereof 2021-09-28
CN-113831272-A Method for synthesizing 2-substituted indole compound by using palladium to catalyze iodobenzene and oxime ester 2021-09-26
CN-113773294-A Preparation method and application of flavone and isoflavone compounds 2021-09-18
CN-113683551-A N-tert-butyl-2-phenylindole derivative, preparation method and application 2021-09-09
CN-113224313-A Metal organic phosphine frame glass modified metal negative current collector and preparation method thereof 2021-04-30
CN-113087691-A Method for synthesizing chiral aryl tertiary alcohol and benzopyran compound based on kinetic resolution strategy 2021-03-26
CN-113372184-A Method for synthesizing C-N axis chiral phenanthridinone compound based on chiral transfer strategy 2021-03-26
CN-113061234-A Benzothiadiazole polymer, electron transport compound and perovskite photoelectric element 2021-03-22
CN-113061235-A Copolymer and organic photovoltaic element 2021-03-22

Literatures

PMID Publication Date Title Journal
22740322 2012-07-27 One-pot approach to installing eight-membered rings onto indoles Angewandte Chemie (International ed. in English)
19317401 2009-04-15 Enhancement of a catalysis-based fluorometric detection method for palladium through rational fine-tuning of the palladium species Journal of the American Chemical Society
18759388 2008-09-24 Branch-selective reductive coupling of 2-vinyl pyridines and imines via rhodium catalyzed C-C bond forming hydrogenation Journal of the American Chemical Society
17107096 2006-11-23 Reductive aldol coupling of divinyl ketones via rhodium-catalyzed hydrogenation: syn-diastereoselective construction of beta-hydroxyenones Organic letters
16435874 2006-02-02 Hydrogen-mediated aldol reductive coupling of vinyl ketones catalyzed by rhodium: high syn-selectivity through the effect of tri-2-furylphosphine Organic letters
15252611 2004-05-21 Unsuccessful/successful attempts to produce penta(heteroaryl)-phosphoranes/-arsoranes R5E (E = P, As; R = 2-furyl, 2-thienyl) Dalton transactions (Cambridge, England : 2003)
14664564 2003-12-17 Palladium-catalyzed Stille cross-couplings of sulfonyl chlorides and organostannanes Journal of the American Chemical Society
12772895 2003-05-07 Palladium catalysed cyclisation-carbonylation of enynes to give cyclic gamma,delta-unsaturated acids Chemical communications (Cambridge, England)
12375972 2002-10-18 Palladium-catalyzed selective synthesis of 2-allyltetrazoles The Journal of organic chemistry
12358538 2002-10-09 Synthesis of allyl cyanamides and N-cyanoindoles via the palladium-catalyzed three-component coupling reaction Journal of the American Chemical Society
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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