Tris(dibenzylideneacetone)dipalladium-chloroForm adduct

Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct (Pd2dba3·CHCl3) was used in the following studies:• To compose the catalytic system for the preparation of homoallylpalladium complexes.These complexes underwent in situ Stille type cross coupling with various vinyltin reagents to afford the cyclized products bearing allyl appendages.• As palladium source in the asymmetric transformations of 3,4-epoxy-1-butene.• As catalyst for the Heck cross-coupling reaction of iodobenzene with styrene.• As cyclization catalyst.• As catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes. • As catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

TRIS(DIBENZYLIDENEACETONE)(CHLOROFORM)-DI-PALLADIUM(0); TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM(0) CHLOROFORM ADDUCT; TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM-CHLOROFORM ADDUCT; TRIS(DIBENZYLIDENEACETONE)DIPALLADIUM CHLOROFORM COMPLEX; DIPALLADIUM(0)TRIS(DIBENZYL

chloroform(1E,4E)-1,5-diphenylpenta-1,4-dien-3-onepalladium

C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C1=CC=C(C=C1)C=CC(=O)C=CC2=CC=CC=C2.C(Cl)(Cl)Cl.[Pd].[Pd]

InChI=1S/3C17H14O.CHCl3.2Pd/c3*18-17(13-11-15-7-3-1-4-8-15)14-12-16-9-5-2-6-10-162-1(3)4/h3*1-14H1H/b3*13-11+,14-12+

LNAMMBFJMYMQTO-FNEBRGMMSA-N

131-135 °C (lit.)

Not applicable

H302 - H315 - H351

P201 - P301 + P312 + P330 - P302 + P352 - P308 + P313