Methanesulfonic acid,1,1,1-trifluoro-, dysprosium(3+) salt (3:1)

Product Information

Molecular Formula:
CH F3 O3 S . 1/3 Dy
Molecular Weight:
609.71
Description
Catalyst for:• Aza-Piancatelli rearrangement• Friedel-Crafts alkylation• Ring-opening polymerization reactions• Microwave-assisted Kabachnik-Fields condensation• Cycloaddition reactions (Lewis-acid catalyst)• Fries rearrangement• Enantioselective glyoxalate-ene reactions
Dysprosium(III) trifluoromethanesulfonate, a water-tolerant Lewis acid, has been used in the following studies:• Aldol reaction of silyl enol ethers with aldehydes. • As an effective catalyst for electrophilic substitution reactions of indoles with imines.• As catalyst for the synthesis of 4-aminocyclopentenones and functionalized azaspirocycles, via intramolecular aza-Piancatelli rearrangement.• As new curing initiator to study the curing of diglycidyl ether of bisphenol-A (DGEBA).
Synonyms
Dysprosium(III) triflate,Tris(triflato)dysprosium
IUPAC Name
dysprosium(3+)trifluoromethanesulfonate
Canonical SMILES
C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].C(F)(F)(F)S(=O)(=O)[O-].[Dy+3]
InChI
InChI=1S/3CHF3O3S.Dy/c3*2-1(3,4)8(5,6)7/h3*(H,5,6,7)/q+3/p-3
InChI Key
XSVCYDUEICANRJ-UHFFFAOYSA-K
Purity
98%

Safety Information

Hazards
H315 - H319 - H335
Precautionary Statement
P302 + P352 - P305 + P351 + P338

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
18
Rotatable Bond Count
0
Exact Mass
610.785254 g/mol
Monoisotopic Mass
610.785254 g/mol
Topological Polar Surface Area
197Ų
Heavy Atom Count
25
Formal Charge
0
Complexity
145
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
4
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-113860366-A Bismuth oxycarbonate/dysprosium oxycarbonate/bismuth oxide composite nanowire electrode material and preparation method thereof 2021-10-18
CN-113501764-A Asymmetric synthesis method of multi-functional cyclopentenone derivative containing trifluoromethyl 2021-07-07
CN-113501766-A Asymmetric synthesis method of multifunctional cyclopentenone derivative containing difluoroalkyl 2021-07-07
CN-113087891-A Oil-soluble polyether and preparation method and application thereof 2021-02-24
WO-2021226009-A1 Synthesis of vinyl cyclobutyl intermediates 2020-05-06
CN-110922321-A Method for preparing gamma-ketene from α, gamma-unsaturated dienone 2019-12-02
CN-113396346-A Optical laminate and flexible display device including the same 2019-09-25
TW-202112558-A Optical laminate and flexible display device including the same 2019-09-25
CN-112390973-A Optical laminate and flexible display device including the same 2019-07-31
US-10759966-B1 Optical laminate and flexible display apparatus comprising the same 2019-07-15
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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