Bis(1,5-cyclooctadiene)nickel(0)
Product Information
Molecular Formula
C16H24Ni
Molecular Weight
275.06
Description
Reactant for:• Oxidative addition reactionsCatalyst for:• Asymmetric α-arylation and heteroarylation of ketones with chloroarenes• Cross-coupling reactions• Regioselective and stereoselective carboxylation/cyclization of allenyl aldehydes under a carbon dioxide atmosphere• Methyl carboxylation of homopropargylic alcohols• Stereoselective borylative ketone-diene coupling• Cycloaddition of benzamides with internal alkynes
Catalyst for the cycloaddition of 1,3-dienes.
Used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. The reaction with terminal acetylenes proceeds in high yield and high selectivity. A variety of functional groups are tolerated.
Catalyst for the cycloaddition of 1,3-dienes.
Used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. The reaction with terminal acetylenes proceeds in high yield and high selectivity. A variety of functional groups are tolerated.
Synonyms
Ni(COD)2,Bis(cyclooctadiene)nickel,Nickel,bis(1,5-cyclooctadiene)-
IUPAC Name
(1Z,5Z)-cycloocta-1,5-dienenickel
SMILES
C1CC=CCCC=C1.C1CC=CCCC=C1.[Ni]
InChI
InChI=1S/2C8H8.Ni/c2*1-2-4-6-8-7-5-3-1;/h2*1-2,7-8H2;
InChI Key
AYHVBQBQROAZHP-UHFFFAOYSA-N
Boiling Point
Decomposes
Melting Point
60 °C (dec.) (lit.)
Flash Point
Not applicable
Purity
99% | 99.9% | 99.99% | 99.999%
Solubility
Decomposes
Appearance
solid
Storage
−20°C
Safety Information
Hazards
H228 - H317 - H332 - H334 - H341 - H351 - H361d - H372 - H410
Precautionary Statement
P201 - P210 - P273 - P280 - P302 + P352 - P308 + P313
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
0
Exact Mass
274.123142 g/mol
Monoisotopic Mass
274.123142 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
17
Formal Charge
0
Complexity
72.6
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
4
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| JP-2022031355-A | Pest control method | 2021-12-15 |
| CN-114181252-A | Synthesis method of chiralphos derivative | 2021-12-13 |
| CN-114032567-A | Electrochemical reduction carboxylation method based on non-sacrificial anode strategy | 2021-11-23 |
| CN-113896864-A | Binuclear organic metal complex and preparation method thereof | 2021-11-16 |
| CN-113831216-A | Synthetic method for preparing monofluoroolefin by taking aldehyde compound as raw material | 2021-10-15 |
| CN-113912516-A | Application of multidentate phosphite ligand in catalytic synthesis of adiponitrile | 2021-10-15 |
| CN-113698327-A | Aryl thioether compounds and preparation method thereof | 2021-10-08 |
| CN-113801298-A | Aminated poly (tetraphenylethylene), and preparation method and application thereof | 2021-10-08 |
| CN-113788765-A | Preparation method of alpha, beta-unsaturated amide | 2021-09-15 |
| CN-113801051-A | Preparation method of N-succinimide | 2021-09-15 |
