1-Methoxy-4-vinyl-benzene
Product Information
Molecular Formula
C9H10O
Molecular Weight
134.18
Description
Employed in the ferric chloride-catalyzed addition of activated methylenes to styrenes.
Synonyms
4-Vinylanisole (stabilized with TBC)
IUPAC Name
1-ethenyl-4-methoxybenzene
SMILES
COC1=CC=C(C=C1)C=C
InChI
InChI=1S/C9H10O/c1-3-8-4-6-9(10-2)7-5-8/h3-7H,1H2,2H3
InChI Key
UAJRSHJHFRVGMG-UHFFFAOYSA-N
Boiling Point
98 °C/18 mmHg
Flash Point
170.6 °CF - closed cup
Purity
>98.0%(GC)
Density
1.009 g/mL at 25 °C (lit.)
Appearance
Colorless to Light yellow to Light orange clear liquid
Storage
0-10°C
Refractive Index
n20/D 1.562 (lit.)
Safety Information
Hazards
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Causes skin irritation.
H319:
Causes serious eye irritation.
Precautionary Statement
P264:
Wash thoroughly after handling.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:
IF ON SKIN:
Wash with plenty of soap and water.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P362+P364:
Take off contaminated clothing. [As modified by IV ATP].
And wash it before reuse. [Added by IV ATP].
Wash thoroughly after handling.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:
IF ON SKIN:
Wash with plenty of soap and water.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P362+P364:
Take off contaminated clothing. [As modified by IV ATP].
And wash it before reuse. [Added by IV ATP].
Computed Properties
XLogP3
3.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
1
Rotatable Bond Count
2
Exact Mass
134.073164938 g/mol
Monoisotopic Mass
134.073164938 g/mol
Topological Polar Surface Area
9.2Ų
Heavy Atom Count
10
Formal Charge
0
Complexity
101
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| US-2021191259-A1 | Colored photosensitive resin composition and black matrix prepared therefrom | 2019-12-24 |
| WO-2021124899-A1 | Polycarbonate-modified acrylic resin, coating material, and molded plastic article coated with said coating material | 2019-12-20 |
| WO-2021125132-A1 | Carbamoyl oxime compound, and polymerization initiator and polymerizable composition containing said compound | 2019-12-20 |
| WO-2021126780-A1 | Combination of crosslinkers to improve coating properties | 2019-12-20 |
| WO-2021127301-A1 | 4-phenyl-n-(phenyl)thiazol-2-amine derivatives and related compounds as aryl hydrocarbon receptor (ahr) agonists for the treatment of e.g. angiogenesis implicated or inflammatory disorders | 2019-12-20 |
| WO-2021125319-A1 | Liquid crystal aligning agent, radical generation film and method for producing in-plane switching liquid crystal cell | 2019-12-18 |
| WO-2021125327-A1 | Method for manufacturing patterned liquid crystal display element | 2019-12-18 |
| WO-2021125329-A1 | Radical generation film-forming composition, radical generation film, and method for manufacturing horizontal-electric-field liquid crystal cell | 2019-12-18 |
| EP-3835330-A1 | Aqueous dispersion of polymer particles and uses thereof as an adhesive composition | 2019-12-13 |
| US-2021181647-A1 | Toner and two component developer | 2019-12-13 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22719431 | 2012-06-01 | 1-(4-Meth-oxy-phen-yl)ethane-1,2-diyl 1,1'-biphenyl-2,2'-dicarboxyl-ate | Acta crystallographica. Section E, Structure reports online |
| 22499396 | 2012-05-28 | A novel quinoline-based two-photon fluorescent probe for detecting Cd2+ in vitro and in vivo | Dalton transactions (Cambridge, England : 2003) |
| 22190469 | 2012-01-23 | Incorporation of manganese complexes into xylanase: new artificial metalloenzymes for enantioselective epoxidation | Chembiochem : a European journal of chemical biology |
| 21132535 | 2011-10-01 | Isolation and identification of a putative scent-related gene RhMYB1 from rose | Molecular biology reports |
| 22022392 | 2011-01-01 | Antifungal activity of resveratrol against Botrytis cinerea is improved using 2-furyl derivatives | PloS one |
| 19957949 | 2010-03-16 | Cationic polymerization of vinyl monomers in aqueous media: from monofunctional oligomers to long-lived polymer chains | Accounts of chemical research |
| 19897904 | 2009-11-01 | Short-step synthesis of a resveratrol derivative from commercially available 1,3-dimethoxybenzene and 4-vinylanisole | Bioscience, biotechnology, and biochemistry |
| 19764759 | 2009-10-14 | Formal [4 + 2] cycloaddition of donor-acceptor cyclobutanes and aldehydes: stereoselective access to substituted tetrahydropyrans | Journal of the American Chemical Society |
| 19663488 | 2009-09-02 | A mechanistic investigation on copolymerization of ethylene with polar monomers using a cyclophane-based Pd(II) alpha-diimine catalyst | Journal of the American Chemical Society |
| 21582840 | 2009-06-13 | N,N'-(Biphenyl-2,2'-di-yl)bis-(furan-2-carboxamide) | Acta crystallographica. Section E, Structure reports online |
