Palladium diacetate

Product Information

Molecular Formula:
Pd.(C2H3O2)2
Molecular Weight:
224.51
Description
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for an intramolecular coupling of aryl bromides with alcohols giving 1,3-oxazepines. Preparation of cyclic ureas via palladium-catalyzed intramolecular cyclization.
Synonyms
ACETIC ACID PALLADIUM(II) SALT; PALLADIUM ACETATE; PALLADIUM(+2)ACETATE; PALLADIUM DIACETATE; PALLADIUM(II) ACETATE; PALLADIUM(II) ACETATE IN IONIC LIQUID ON SILICA
IUPAC Name
palladium(2+)diacetate
Canonical SMILES
CC(=O)[O-].CC(=O)[O-].[Pd+2]
InChI
InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI Key
YJVFFLUZDVXJQI-UHFFFAOYSA-L
Boiling Point
117.1°C at 760mmHg
Melting Point
205°C
Flash Point
Not applicable
Purity
98%
Appearance
brown needles
Application
Used as a catalyst in organic chemistry.
Storage
Store at R.T.

Safety Information

Hazards
H318
Precautionary Statement
P280 - P305 + P351 + P338 + P310
Signal Word
Danger

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
0
Exact Mass
223.93009 g/mol
Monoisotopic Mass
223.93009 g/mol
Topological Polar Surface Area
80.3Ų
Heavy Atom Count
9
Formal Charge
0
Complexity
25.5
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
US-2016038908-A1 Method and system for flammable gas detection 2014-08-07
US-2016043331-A1 Metal-assisted delayed fluorescent emitters containing tridentate ligands 2014-07-29
US-2015194616-A1 Tetradentate Platinum And Palladium Complex Emitters Containing Phenyl-Pyrazole And Its Analogues 2014-01-07
US-2014018538-A1 High-valent palladium fluoride complexes and uses thereof 2010-08-20
US-9434812-B2 Dyketopyrrolopyrrole polymers for use in organic semiconductor devices 2010-05-19
US-2013096119-A1 Isoquinolin-3-Ylurea Derivatives 2010-03-31
US-2014058106-A1 System for fluorinating organic compounds 2008-01-31
US-2009221820-A1 Ligands for Transition-Metal-Catalyzed Cross-Couplings, and Methods of Use Thereof 2007-12-12
US-7858784-B2 Ligands for transition-metal-catalyzed cross-couplings, and methods of use thereof 2007-12-12
US-2009030238-A1 System for controlling the reactivity of boronic acids 2007-07-23

Literatures

PMID Publication Date Title Journal
23002697 2012-10-16 Grafting control of mainstay terpyridine self-assembled monolayers for the preparation of planar silicon surfaces with variable catalytic loadings Langmuir : the ACS journal of surfaces and colloids
22581281 2012-06-21 Palladium(II) acetate mediated oxidative cyclization of ω-unsaturated α-cyano ketones for facile construction of methylenecyclohexane ring system Organic & biomolecular chemistry
21858353 2012-02-01 Palladium-catalyzed hydroacyloxylation of ynamides Chemical communications (Cambridge, England)
21806046 2011-09-05 Regioselective orthopalladation of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones: scope, kinetico-mechanistic, and density functional theory studies of the C-H bond activation Inorganic chemistry
20953496 2010-12-14 Tetrasubstituted furans by Pd(II)/Cu(I)-cocatalyzed three-component domino reactions of 2-(1-alkynyl)-2-alken-1-ones, nucleophiles and diaryliodonium salts Chemical communications (Cambridge, England)
20652185 2010-09-21 Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system Organic & biomolecular chemistry
20681516 2010-09-13 Efficient assembly of 1-methylene-1H-indenes via palladium-catalyzed tandem reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene with arylboronic acid Journal of combinatorial chemistry
20401375 2010-05-07 Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers Organic & biomolecular chemistry
20225875 2010-04-07 Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes Journal of the American Chemical Society
20428035 2010-03-25 Selective Heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts Molecules (Basel, Switzerland)
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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