Palladium diacetate
Product Information
Molecular Formula
Pd.(C2H3O2)2
Molecular Weight
224.51
Description
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Catalyst for an intramolecular coupling of aryl bromides with alcohols giving 1,3-oxazepines. Preparation of cyclic ureas via palladium-catalyzed intramolecular cyclization.
Catalyst for an intramolecular coupling of aryl bromides with alcohols giving 1,3-oxazepines. Preparation of cyclic ureas via palladium-catalyzed intramolecular cyclization.
Synonyms
ACETIC ACID PALLADIUM(II) SALT; PALLADIUM ACETATE; PALLADIUM(+2)ACETATE; PALLADIUM DIACETATE; PALLADIUM(II) ACETATE; PALLADIUM(II) ACETATE IN IONIC LIQUID ON SILICA
IUPAC Name
palladium(2+)diacetate
SMILES
CC(=O)[O-].CC(=O)[O-].[Pd+2]
InChI
InChI=1S/2C2H4O2.Pd/c2*1-2(3)4;/h2*1H3,(H,3,4);/q;;+2/p-2
InChI Key
YJVFFLUZDVXJQI-UHFFFAOYSA-L
Boiling Point
117.1°C at 760mmHg
Melting Point
205°C
Flash Point
Not applicable
Purity
98%
Appearance
brown needles
Application
Used as a catalyst in organic chemistry.
Storage
Store at R.T.
Safety Information
Hazards
H318
Precautionary Statement
P280 - P305 + P351 + P338 + P310
Signal Word
Danger
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
0
Exact Mass
223.93009 g/mol
Monoisotopic Mass
223.93009 g/mol
Topological Polar Surface Area
80.3Ų
Heavy Atom Count
9
Formal Charge
0
Complexity
25.5
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| US-2016038908-A1 | Method and system for flammable gas detection | 2014-08-07 |
| US-2016043331-A1 | Metal-assisted delayed fluorescent emitters containing tridentate ligands | 2014-07-29 |
| US-2015194616-A1 | Tetradentate Platinum And Palladium Complex Emitters Containing Phenyl-Pyrazole And Its Analogues | 2014-01-07 |
| US-2014018538-A1 | High-valent palladium fluoride complexes and uses thereof | 2010-08-20 |
| US-9434812-B2 | Dyketopyrrolopyrrole polymers for use in organic semiconductor devices | 2010-05-19 |
| US-2013096119-A1 | Isoquinolin-3-Ylurea Derivatives | 2010-03-31 |
| US-2014058106-A1 | System for fluorinating organic compounds | 2008-01-31 |
| US-2009221820-A1 | Ligands for Transition-Metal-Catalyzed Cross-Couplings, and Methods of Use Thereof | 2007-12-12 |
| US-7858784-B2 | Ligands for transition-metal-catalyzed cross-couplings, and methods of use thereof | 2007-12-12 |
| US-2009030238-A1 | System for controlling the reactivity of boronic acids | 2007-07-23 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 23002697 | 2012-10-16 | Grafting control of mainstay terpyridine self-assembled monolayers for the preparation of planar silicon surfaces with variable catalytic loadings | Langmuir : the ACS journal of surfaces and colloids |
| 22581281 | 2012-06-21 | Palladium(II) acetate mediated oxidative cyclization of ω-unsaturated α-cyano ketones for facile construction of methylenecyclohexane ring system | Organic & biomolecular chemistry |
| 21858353 | 2012-02-01 | Palladium-catalyzed hydroacyloxylation of ynamides | Chemical communications (Cambridge, England) |
| 21806046 | 2011-09-05 | Regioselective orthopalladation of (Z)-2-aryl-4-arylidene-5(4H)-oxazolones: scope, kinetico-mechanistic, and density functional theory studies of the C-H bond activation | Inorganic chemistry |
| 20953496 | 2010-12-14 | Tetrasubstituted furans by Pd(II)/Cu(I)-cocatalyzed three-component domino reactions of 2-(1-alkynyl)-2-alken-1-ones, nucleophiles and diaryliodonium salts | Chemical communications (Cambridge, England) |
| 20652185 | 2010-09-21 | Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system | Organic & biomolecular chemistry |
| 20681516 | 2010-09-13 | Efficient assembly of 1-methylene-1H-indenes via palladium-catalyzed tandem reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene with arylboronic acid | Journal of combinatorial chemistry |
| 20401375 | 2010-05-07 | Efficient synthesis of alkyl aryl ketones & ketals via palladium-catalyzed regioselective arylation of vinyl ethers | Organic & biomolecular chemistry |
| 20225875 | 2010-04-07 | Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes | Journal of the American Chemical Society |
| 20428035 | 2010-03-25 | Selective Heck arylation of cyclohexene with homogeneous and heterogeneous palladium catalysts | Molecules (Basel, Switzerland) |
