Palladium(II) Chloride

Product Information

Molecular Formula:
PdCl2
Molecular Weight:
177.31
Description
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Synonyms
Palladium chloride (PdCl2); dichloropalladium; Palladium(II) Chloride
IUPAC Name
dichloropalladium
Canonical SMILES
Cl[Pd]Cl
InChI
InChI=1S/2ClH.Pd/h2*1H/q+2/p-2
InChI Key
PIBWKRNGBLPSSY-UHFFFAOYSA-L
Melting Point
678-680°C
Purity
95%
Solubility
Soluble (NTP, 1992); Sol in water, ethanol, acetone; Readily soluble in hydrochloric acid and solutions of alkali metal chlorides.
Appearance
dark brown powder
Application
C-H Activation; Carbonylation; Cross Coupling Reactions with Arenes→Mizoroki Heck Coupling Reaction; Oxidation;
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Stability
Stable. Incompatible with strong oxidizing agents.
LogP
1.37900
Decomposition
When heated to decomposition it emits highly toxic fumes of /hydrogen chloride.

Safety Information

Hazards
H290 - H302 - H317 - H318 - H410
Precautionary Statement
P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
0
Exact Mass
175.84119 g/mol
Monoisotopic Mass
175.84119 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
3
Formal Charge
0
Complexity
2.8
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
US-2016128973-A1 Inhibition of cancer cell motility 2014-11-06
US-2014221354-A1 IMIDAZO [1,2-a]PYRIDINE COMPOUNDS FOR USE IN THERAPY 2011-03-31
US-2014048738-A1 Nano particle/polyamide composite material, preparation method therefor, and use thereof 2010-12-28
US-9355765-B2 Nano particle/polyamide composite material, preparation method therefor, and use thereof 2010-12-28
US-2012028957-A1 Inhibitors Of The Influenza A Virus M2 Proton Channel 2010-08-01
US-2012028969-A1 Bicyclic acetyl-coa carboxylase inhibitors and uses thereof 2010-07-29
US-2012028923-A1 Compositions and methods for inhibition of the jak pathway 2010-07-28
US-2012001127-A1 Hole transport compositions and related devices and methods (i) 2010-07-02
US-2012003790-A1 Hole transport compositions and related devices amd methods (ii) 2010-07-02
US-2011313183-A1 Method for preparation of n-methyl-3-(2-tributylstannylphenoxy)-3-phenylpropanamine, and use therof 2010-06-22

Literatures

PMID Publication Date Title Journal
22428585 2012-11-01 Contact allergy to metals in adolescents: nickel release from metal accessories 7 years after the implementation of the EU Nickel Directive in Poland Contact dermatitis
22934626 2012-09-21 Pd(II)-mediated cyclization of o-allylbenzaldehydes in water: a novel synthesis of isocoumarins Organic letters
22582939 2012-06-01 PdCl2-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones Organic letters
22473222 2012-05-16 Synthesis of 4H-cyclopenta[c]furans via cooperative PdCl2-FeCl2 catalyzed cascade cyclization reaction involving a novel acyl rearrangement process Chemical communications (Cambridge, England)
22286057 2012-04-01 Spectrophotometric complexation of cephalosporins with palladium (II) chloride in aqueous and non-aqueous solvents Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy
22068915 2012-01-14 Crystal structure, electronic properties and cytotoxic activity of palladium chloride complexes with monosubstituted pyridines Dalton transactions (Cambridge, England : 2003)
22095621 2011-12-16 An efficient palladium catalyst system for the oxidative carbonylation of glycerol to glycerol carbonate ChemSusChem
22027127 2011-11-30 Interaction of adenine with palladium chloride, determination of adenine via resonance Rayleigh scattering method Analytica chimica acta
21981005 2011-11-07 Flexible diphosphine ligands with overall charges of 0, +1, and +2: critical role of the electrostatics in favoring trans over cis coordination Inorganic chemistry
21788930 2011-07-25 The Suzuki reaction in aqueous media promoted by P, N ligands Molecules (Basel, Switzerland)
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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