Palladium(II) Chloride
Product Information
Molecular Formula
PdCl2
Molecular Weight
177.31
Description
Application Guide for Palladium Catalyzed Cross-Coupling ReactionsUsed in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.
Synonyms
Palladium chloride (PdCl2); dichloropalladium; Palladium(II) Chloride
IUPAC Name
dichloropalladium
SMILES
Cl[Pd]Cl
InChI
InChI=1S/2ClH.Pd/h2*1H/q+2/p-2
InChI Key
PIBWKRNGBLPSSY-UHFFFAOYSA-L
Melting Point
678-680°C
Purity
95%
Solubility
Soluble (NTP, 1992); Sol in water, ethanol, acetone; Readily soluble in hydrochloric acid and solutions of alkali metal chlorides.
Appearance
dark brown powder
Application
C-H Activation; Carbonylation; Cross Coupling Reactions with Arenes→Mizoroki Heck Coupling Reaction; Oxidation;
Storage
Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Store protected from moisture.
Stability
Stable. Incompatible with strong oxidizing agents.
LogP
1.37900
Decomposition
When heated to decomposition it emits highly toxic fumes of /hydrogen chloride.
Safety Information
Hazards
H290 - H302 - H317 - H318 - H410
Precautionary Statement
P273 - P280 - P301 + P312 + P330 - P302 + P352 - P305 + P351 + P338 + P310
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
0
Exact Mass
175.84119 g/mol
Monoisotopic Mass
175.84119 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
3
Formal Charge
0
Complexity
2.8
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| US-2016128973-A1 | Inhibition of cancer cell motility | 2014-11-06 |
| US-2014221354-A1 | IMIDAZO [1,2-a]PYRIDINE COMPOUNDS FOR USE IN THERAPY | 2011-03-31 |
| US-2014048738-A1 | Nano particle/polyamide composite material, preparation method therefor, and use thereof | 2010-12-28 |
| US-9355765-B2 | Nano particle/polyamide composite material, preparation method therefor, and use thereof | 2010-12-28 |
| US-2012028957-A1 | Inhibitors Of The Influenza A Virus M2 Proton Channel | 2010-08-01 |
| US-2012028969-A1 | Bicyclic acetyl-coa carboxylase inhibitors and uses thereof | 2010-07-29 |
| US-2012028923-A1 | Compositions and methods for inhibition of the jak pathway | 2010-07-28 |
| US-2012001127-A1 | Hole transport compositions and related devices and methods (i) | 2010-07-02 |
| US-2012003790-A1 | Hole transport compositions and related devices amd methods (ii) | 2010-07-02 |
| US-2011313183-A1 | Method for preparation of n-methyl-3-(2-tributylstannylphenoxy)-3-phenylpropanamine, and use therof | 2010-06-22 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22428585 | 2012-11-01 | Contact allergy to metals in adolescents: nickel release from metal accessories 7 years after the implementation of the EU Nickel Directive in Poland | Contact dermatitis |
| 22934626 | 2012-09-21 | Pd(II)-mediated cyclization of o-allylbenzaldehydes in water: a novel synthesis of isocoumarins | Organic letters |
| 22582939 | 2012-06-01 | PdCl2-catalyzed oxidative cycloisomerization of 3-cyclopropylideneprop-2-en-1-ones | Organic letters |
| 22473222 | 2012-05-16 | Synthesis of 4H-cyclopenta[c]furans via cooperative PdCl2-FeCl2 catalyzed cascade cyclization reaction involving a novel acyl rearrangement process | Chemical communications (Cambridge, England) |
| 22286057 | 2012-04-01 | Spectrophotometric complexation of cephalosporins with palladium (II) chloride in aqueous and non-aqueous solvents | Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy |
| 22068915 | 2012-01-14 | Crystal structure, electronic properties and cytotoxic activity of palladium chloride complexes with monosubstituted pyridines | Dalton transactions (Cambridge, England : 2003) |
| 22095621 | 2011-12-16 | An efficient palladium catalyst system for the oxidative carbonylation of glycerol to glycerol carbonate | ChemSusChem |
| 22027127 | 2011-11-30 | Interaction of adenine with palladium chloride, determination of adenine via resonance Rayleigh scattering method | Analytica chimica acta |
| 21981005 | 2011-11-07 | Flexible diphosphine ligands with overall charges of 0, +1, and +2: critical role of the electrostatics in favoring trans over cis coordination | Inorganic chemistry |
| 21788930 | 2011-07-25 | The Suzuki reaction in aqueous media promoted by P, N ligands | Molecules (Basel, Switzerland) |
