poly(chlorotrifluoroethylene)

Product Information

Molecular Formula:
(C2ClF3)n
Molecular Weight:
116.47
Description
Chemical resistance, near-zero moisture absorption, low creep, high optical transparency, high electrical insulating capacity, non-flammable and low coefficient of thermal expansion.
Synonyms
Poly(trifluorochloroethylene); Poly(monochlorotrifluoroethylene); Chlorotrifluoroethylene homopolymer
IUPAC Name
1-chloro-1,2,2-trifluoroethene
Canonical SMILES
C(=C(F)Cl)(F)F
InChI
InChI=1S/C2ClF3/c3-1(4)2(5)6
InChI Key
UUAGAQFQZIEFAH-UHFFFAOYSA-N
Boiling Point
-18 °F at 760 mmHg
Melting Point
Tm (DSC) 210 °C (onset)
Flash Point
-27.8 °C
Purity
95%
Solubility
water, 4013 mg/L @ 25 °C (est)
Appearance
White powder or formed articles
Application
Used to make chlorotrifluoroethylene resins (Kel-F, Halar); Used in the synthesis of lubricants, plastics, elastomers, and other chemical products.
Tg
Tg (DSC) 103 °C (onset)
LogP
log Kow = 1.65 (est)
Vapor Pressure
4590.0 [mmHg]
Henry's Law Constant
0.311 atm-cu m/mol at 25 °C (est)
Decomposition
When heated to decomposition it emits toxic fumes of /fluorine/ and /chlorine.
Odor
Faint etheral odor

Safety Information

Hazards
n20/D 1.415
Handling
at 100° F (37.8 °C): 1.000 centistokes (1.950 cPs)

Computed Properties

XLogP3
1.9
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
0
Exact Mass
115.9640622 g/mol
Monoisotopic Mass
115.9640622 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
6
Formal Charge
0
Complexity
72.9
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114085521-A Copolymerized nylon polymer and preparation method thereof 2021-12-20
CN-114161874-A Method for reinforcing and displaying stone colored drawing 2021-12-10
JP-2022033143-A Manufacturing method of composite rubber molded body for pharmaceuticals 2021-12-03
CN-113955840-A Method for removing chlorinated hydrocarbons in underground water of industrial site in enhanced mode through combination of zero-valent magnesium and chemical characteristics of underground water 2021-11-30
CN-114031744-A Diisocyanate carbomethoxycyclohexane composition, modified composition thereof and preparation method 2021-11-29
CN-113930119-A Water-based paint applied to aluminum-plastic plates and color steel coiled materials 2021-11-25
CN-113956593-A Modified low-pressure variable fluororubber, preparation method thereof and rubber compound 2021-11-23
CN-114181481-A Screening method and application for preparing multilayer PTFE composite expanded sheet material, expanded sheet and preparation method thereof 2021-11-23
CN-113929825-A Carboxylic styrene-butadiene latex for building coating and preparation method thereof 2021-11-19
CN-114133475-A Fluorine-containing anion and nonionic mixed polymerizable emulsifier, preparation method and application thereof in aqueous fluorocarbon resin synthesis 2021-11-18

Literatures

PMID Publication Date Title Journal
22691065 2012-07-06 Pd-catalyzed arylation of chlorotrifluoroethylene using arylboronic acids Organic letters
22025988 2011-10-01 Combined third-harmonic generation and four-wave mixing microscopy of tissues and embryos Biomedical optics express
21655553 2011-07-21 Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether under 60Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate Chemical communications (Cambridge, England)
21432976 2011-01-03 Greatly enhanced energy density and patterned films induced by photo cross-linking of poly(vinylidene fluoride-chlorotrifluoroethylene) Macromolecular rapid communications
19668707 2009-01-01 Adhesion molecule-modified biomaterials for neural tissue engineering Frontiers in neuroengineering
18665264 2008-07-30 High-resolution, in vivo magnetic resonance imaging of Drosophila at 18.8 Tesla PloS one
17678406 2007-07-27 Phase equilibria in high energy density PVDF-based polymers Physical review letters
17372960 2007-05-01 Solid-state 19F MAS NMR study on the conformation and molecular mobility of poly(chlorotrifluoroethylene) Magnetic resonance in chemistry : MRC
16787060 2006-06-28 A modular approach to ferroelectric polymers with chemically tunable curie temperatures and dielectric constants Journal of the American Chemical Society
16182853 2005-10-01 Reductive dechlorination of chlorofluorocarbons and hydrochlorofluorocarbons in sewage sludge and aquifer sediment microcosms Chemosphere
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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