Tri-n-octylphosphine
Product Information
Molecular Formula
C24H51P
Molecular Weight
370.64
Description
Trioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides. It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.
Synonyms
CYTOP(R) 380; TRIOCTYLPHOSPHINE; TRI-N-OCTYLPHOSPHINE; nsc102529; tl411; trioctyl-phosphin
IUPAC Name
trioctylphosphane
SMILES
CCCCCCCCP(CCCCCCCC)CCCCCCCC
InChI
InChI=1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
InChI Key
RMZAYIKUYWXQPB-UHFFFAOYSA-N
Boiling Point
284 - 291°C at 50 mm Hg
Melting Point
-60°C
Flash Point
296.6 °F - closed cup
Purity
>85.0%(GC)
Density
0.831
Appearance
Colorless to yellow liquid
Refractive Index
n20/D 1.468 (lit.)
Safety Information
Hazards
H314
Precautionary Statement
P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338
Computed Properties
XLogP3
10.2
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
21
Exact Mass
370.37283862 g/mol
Monoisotopic Mass
370.37283862 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
25
Formal Charge
0
Complexity
188
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114058368-A | Alloyed core-shell structure quantum dot and preparation method thereof | 2021-12-20 |
| CN-114184786-A | Kit for rapidly detecting human immunodeficiency virus and application thereof | 2021-12-16 |
| CN-114184787-A | Kit for rapidly detecting human immunodeficiency virus and application thereof | 2021-12-16 |
| JP-2022040133-A | A photosensitive coloring composition for a color filter for a solid-state image sensor, a color filter, and a solid-state image sensor using the same. | 2021-12-15 |
| CN-113998676-A | Method for preparing mercury selenide nanocrystalline by solvothermal method | 2021-12-10 |
| CN-114032102-A | Quantum dot, preparation method thereof and quantum dot film | 2021-12-10 |
| CN-114188490-A | Quantum dot-semiconductor composite film layer, preparation method thereof and quantum dot light-emitting device | 2021-12-10 |
| CN-114171708-A | Preparation method of QLED display panel and QLED display panel | 2021-12-07 |
| CN-114188489-A | Quantum dot light emitting layer and preparation method thereof, QLED device and display device | 2021-12-03 |
| CN-114147222-A | Chiral metal-semiconductor heterogeneous nano material and preparation method thereof | 2021-12-02 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 23009087 | 2012-10-23 | Quenching dynamics in CdSe nanoparticles: surface-induced defects upon dilution | ACS nano |
| 22845819 | 2012-09-12 | Unintended phosphorus doping of nickel nanoparticles during synthesis with TOP: a discovery through structural analysis | Nano letters |
| 22829060 | 2012-09-07 | Synthesis of lead chalcogenide nanocrystals and study of charge transfer in blends of PbSe nanocrystals and poly(3-hexylthiophene) | Physical chemistry chemical physics : PCCP |
| 23035471 | 2012-09-01 | Photoluminescent enhancement of CdSe/Cd(1-x) Zn(x)S quantum dots by hexadecylamine at room temperature | Journal of nanoscience and nanotechnology |
| 22777138 | 2012-08-28 | Carbonate, acetate and phenolate phosphonium salts as catalysts in transesterification reactions for the synthesis of non-symmetric dialkyl carbonates | Organic & biomolecular chemistry |
| 22749581 | 2012-08-03 | Hollow-fiber liquid phase microextraction for lignin pyrolysis acids in aerosol samples and gas chromatography-mass spectrometry analysis | Journal of chromatography. A |
| 22519805 | 2012-06-26 | Molecular control of the nanoscale: effect of phosphine-chalcogenide reactivity on CdS-CdSe nanocrystal composition and morphology | ACS nano |
| 22380657 | 2012-04-03 | Nanopatterned cadmium selenide Langmuir-Blodgett platform for leukemia detection | Analytical chemistry |
| 22080053 | 2012-02-27 | Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2}2] for the formation of nickel-containing nanoparticles | Dalton transactions (Cambridge, England : 2003) |
| 22268842 | 2012-02-08 | n-Type nanostructured thermoelectric materials prepared from chemically synthesized ultrathin Bi2Te3 nanoplates | Nano letters |
