Tri-n-octylphosphine

Product Information

Molecular Formula:
C24H51P
Molecular Weight:
370.64
Description
Trioctylphosphine can be used for the conversion of metal nanocrystals, bulk powders, foils, wires, thin films to metal phosphides. It can also act as a solvent and stabilizer for synthesizing cadmium sulfide nanorods from cadmium acetate and sulfur.
Synonyms
CYTOP(R) 380; TRIOCTYLPHOSPHINE; TRI-N-OCTYLPHOSPHINE; nsc102529; tl411; trioctyl-phosphin
IUPAC Name
trioctylphosphane
Canonical SMILES
CCCCCCCCP(CCCCCCCC)CCCCCCCC
InChI
InChI=1S/C24H51P/c1-4-7-10-13-16-19-22-25(23-20-17-14-11-8-5-2)24-21-18-15-12-9-6-3/h4-24H2,1-3H3
InChI Key
RMZAYIKUYWXQPB-UHFFFAOYSA-N
Boiling Point
284 - 291°C at 50 mm Hg
Melting Point
-60°C
Flash Point
296.6 °F - closed cup
Purity
>85.0%(GC)
Density
0.831
Appearance
Colorless to yellow liquid
Refractive Index
n20/D 1.468 (lit.)

Safety Information

Hazards
H314
Precautionary Statement
P280 - P301 + P330 + P331 - P303 + P361 + P353 - P305 + P351 + P338

Computed Properties

XLogP3
10.2
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
21
Exact Mass
370.37283862 g/mol
Monoisotopic Mass
370.37283862 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
25
Formal Charge
0
Complexity
188
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114058368-A Alloyed core-shell structure quantum dot and preparation method thereof 2021-12-20
CN-114184786-A Kit for rapidly detecting human immunodeficiency virus and application thereof 2021-12-16
CN-114184787-A Kit for rapidly detecting human immunodeficiency virus and application thereof 2021-12-16
JP-2022040133-A A photosensitive coloring composition for a color filter for a solid-state image sensor, a color filter, and a solid-state image sensor using the same. 2021-12-15
CN-113998676-A Method for preparing mercury selenide nanocrystalline by solvothermal method 2021-12-10
CN-114032102-A Quantum dot, preparation method thereof and quantum dot film 2021-12-10
CN-114188490-A Quantum dot-semiconductor composite film layer, preparation method thereof and quantum dot light-emitting device 2021-12-10
CN-114171708-A Preparation method of QLED display panel and QLED display panel 2021-12-07
CN-114188489-A Quantum dot light emitting layer and preparation method thereof, QLED device and display device 2021-12-03
CN-114147222-A Chiral metal-semiconductor heterogeneous nano material and preparation method thereof 2021-12-02

Literatures

PMID Publication Date Title Journal
23009087 2012-10-23 Quenching dynamics in CdSe nanoparticles: surface-induced defects upon dilution ACS nano
22845819 2012-09-12 Unintended phosphorus doping of nickel nanoparticles during synthesis with TOP: a discovery through structural analysis Nano letters
22829060 2012-09-07 Synthesis of lead chalcogenide nanocrystals and study of charge transfer in blends of PbSe nanocrystals and poly(3-hexylthiophene) Physical chemistry chemical physics : PCCP
23035471 2012-09-01 Photoluminescent enhancement of CdSe/Cd(1-x) Zn(x)S quantum dots by hexadecylamine at room temperature Journal of nanoscience and nanotechnology
22777138 2012-08-28 Carbonate, acetate and phenolate phosphonium salts as catalysts in transesterification reactions for the synthesis of non-symmetric dialkyl carbonates Organic & biomolecular chemistry
22749581 2012-08-03 Hollow-fiber liquid phase microextraction for lignin pyrolysis acids in aerosol samples and gas chromatography-mass spectrometry analysis Journal of chromatography. A
22519805 2012-06-26 Molecular control of the nanoscale: effect of phosphine-chalcogenide reactivity on CdS-CdSe nanocrystal composition and morphology ACS nano
22380657 2012-04-03 Nanopatterned cadmium selenide Langmuir-Blodgett platform for leukemia detection Analytical chemistry
22080053 2012-02-27 Influence of the coordination mode in [Ni{RC(S)NP(S)(OiPr)2}2] for the formation of nickel-containing nanoparticles Dalton transactions (Cambridge, England : 2003)
22268842 2012-02-08 n-Type nanostructured thermoelectric materials prepared from chemically synthesized ultrathin Bi2Te3 nanoplates Nano letters
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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