Tri(p-tolyl)phosphine
Product Information
Molecular Formula
C21H21P
Molecular Weight
304.37
Description
Tri(p-tolyl)phosphine (CAS# 1038-95-5) is a useful research chemical.
Synonyms
tris(4-methylphenyl)phosphine; tris(4-methylphenyl)phosphane
IUPAC Name
tris(4-methylphenyl)phosphane
SMILES
CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=C(C=C3)C
InChI
InChI=1S/C21H21P/c1-16-4-10-19(11-5-16)22(20-12-6-17(2)7-13-20)21-14-8-18(3)9-15-21/h4-15H,1-3H3
InChI Key
WXAZIUYTQHYBFW-UHFFFAOYSA-N
Melting Point
144-148 °C (lit.)
Flash Point
Not applicable
Purity
98 %
Storage
Inert atmosphere, Room Temperature
LogP
4.37000
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
5.7
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
3
Exact Mass
304.138087668 g/mol
Monoisotopic Mass
304.138087668 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
22
Formal Charge
0
Complexity
263
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113980044-A | Preparation method of Ir-O-P type catalyst diboronic acid/ester compound | 2021-12-03 |
| CN-113996340-A | Novel catalyst system for hydroformylation reaction and hydroformylation reaction method | 2021-11-16 |
| CN-113698431-A | Synthesis method of phosphine (III) compound | 2021-09-27 |
| CN-113651665-A | Preparation method of myrcene | 2021-08-23 |
| CN-113429286-A | Method for synthesizing polysubstituted biaryl derivative by using aryl diazonium salt | 2021-08-04 |
| CN-113402850-A | Low-dielectric-constant and low-warpage epoxy plastic packaging material composition, preparation and application | 2021-07-13 |
| CN-113233992-A | Preparation method of 5-chloro-4-acetamido-2-methoxybenzoic acid methyl ester | 2021-05-13 |
| CN-113224313-A | Metal organic phosphine frame glass modified metal negative current collector and preparation method thereof | 2021-04-30 |
| CN-113045371-A | Synthetic method of diaryl methyl sulfide derivative catalyzed by organic phosphine | 2021-03-22 |
| JP-2021080483-A | Complex | 2021-03-04 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22199491 | 2011-12-01 | trans-Carbonyl-chloridobis(tri-o-tolyl-phosphane-κP)rhodium(I) | Acta crystallographica. Section E, Structure reports online |
| 21522754 | 2010-12-08 | Tris(4-methyl-phen-yl)phosphine selenide | Acta crystallographica. Section E, Structure reports online |
| 20023954 | 2010-01-07 | Synthesis of InP nanofibers from tri(m-tolyl)phosphine: an alternative route to metal phosphide nanostructures | Dalton transactions (Cambridge, England : 2003) |
| 20379345 | 2010-01-01 | Structural properties, cytotoxicity, and anti-inflammatory activity of silver(I) complexes with tris(p-tolyl)phosphine and 5-chloro-2-mercaptobenzothiazole | Bioinorganic chemistry and applications |
| 21579935 | 2009-12-09 | [μ-Bis(diphenyl-arsino)methane-1:2κAs:As']nona-carbonyl-1κC,2κC,3κC-[tris-(4-methyl-phen-yl)-phosphine-3κP]-triangulo-triruthenium(0) | Acta crystallographica. Section E, Structure reports online |
| 19923698 | 2009-12-01 | Isomorphism in monomeric 1:3 complexes of silver(I) salts with tri-p-tolylphosphine | Acta crystallographica. Section B, Structural science |
| 19299874 | 2009-04-01 | Polymorphism in iodotris(tri-p-tolylphosphine)silver(I) | Acta crystallographica. Section B, Structural science |
| 21201763 | 2008-08-20 | Tri-p-tolyl-phosphine | Acta crystallographica. Section E, Structure reports online |
| 17902651 | 2008-04-21 | Photophysics of diplatinum polyynediyl oligomers: chain length dependence of the triplet state in sp carbon chains | Inorganic chemistry |
| 15792495 | 2005-04-04 | New oxorhenium(V) compound for catalyzed oxygen atom transfer from picoline N-oxide to triarylphosphines | Inorganic chemistry |
