Triethylphosphine
Product Information
Molecular Formula
C6H15P
Molecular Weight
118.16
Description
Triethylphosphine is generally used as a ligand in the organometallic chemistry. It can be used in:• Synthesis of the tetrahedrally coordinated L3Fe-Nx complex with a terminal nitride group.• Synthesis of (PEt3)2Ni(η2-C14H10), a source of the reactive Ni(PEt3)2 moiety.• Synthesis of dinuclear rhodium complexes with triethyllphosphane bridges.
Synonyms
AURORA KA-1111; CYTOP(R) 320; TRIETHYLPHOSPHINE; (C2H5)3P; Phosphorus triethyl; tl409; triethylphosphane; Triethyl-phosphane
IUPAC Name
triethylphosphane
SMILES
CCP(CC)CC
InChI
InChI=1S/C6H15P/c1-4-7(5-2)6-3/h4-6H2,1-3H3
InChI Key
RXJKFRMDXUJTEX-UHFFFAOYSA-N
Boiling Point
127-128°C
Melting Point
-3°C
Flash Point
-4.0 °F - closed cup
Purity
95%
Density
0.802
Appearance
clear liquid
Application
Used in organic syntheses.
Storage
Flammables-area.
Refractive Index
n20/D 1.456 (lit.)
Safety Information
Hazards
H250 - H314
Precautionary Statement
P231 + P232 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P370 + P378
Computed Properties
XLogP3
1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
3
Exact Mass
118.091137476 g/mol
Monoisotopic Mass
118.091137476 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
7
Formal Charge
0
Complexity
25.7
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113735902-A | C15 phosphine salt isomer and preparation method and application thereof | 2021-10-11 |
| CN-113816925-A | A trematopsin 3 "-tert-butyl-4 '- (2-hydroxyethoxy) -4" -pyrrolidin-1-yl [1, 1'; process for preparing 3 ', 1' ] -terphenyl-4-carboxylic acid | 2021-09-18 |
| CN-113651743-A | Preparation method of beta-carotene | 2021-08-30 |
| CN-113461539-A | Method for preparing organic diamine from amino nitrile organic matter | 2021-08-02 |
| CN-113441166-A | Nitrogen-phosphorus co-doped carbon-based cobalt catalyst, preparation method thereof and synthesis method of saturated aliphatic primary amine | 2021-08-02 |
| CN-113582853-A | Method and device for preparing organic diamine from organic amide | 2021-08-02 |
| CN-113461948-A | Flash rust prevention agent and preparation method and application thereof | 2021-07-12 |
| CN-113499799-A | Application of alkylidene carbene ruthenium metal complex in hydrogen production by catalyzing hydrogen storage carrier | 2021-06-23 |
| CN-113321571-A | Synthesis method of linear dihydric alcohol | 2021-06-21 |
| CN-113201016-A | Preparation method of C15 phosphonium salt | 2021-05-19 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 23035689 | 2012-10-15 | Syntheses and electronic properties of rhodium(III) complexes bearing a redox-active ligand | Inorganic chemistry |
| 22455750 | 2012-04-11 | Dispersion energy enforced dimerization of a cyclic disilylated plumbylene | Journal of the American Chemical Society |
| 22192797 | 2011-12-22 | Proteomic analysis of endothelial cold-adaptation | BMC genomics |
| 22052590 | 2011-12-09 | Assembling phthalocyanine dimers through a platinum(II) acetylide linker | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 21843342 | 2011-08-15 | Comparison of genomic and proteomic data in recurrent airway obstruction affected horses using Ingenuity Pathway Analysis® | BMC veterinary research |
| 21619653 | 2011-05-27 | A large, consistent plasma proteomics data set from prospectively collected breast cancer patient and healthy volunteer samples | Journal of translational medicine |
| 21533132 | 2011-04-20 | Systems-scale analysis reveals pathways involved in cellular response to methamphetamine | PloS one |
| 21077686 | 2011-01-13 | Organometallic anticancer compounds | Journal of medicinal chemistry |
| 22084690 | 2011-01-01 | Proteomic Characterization of Cerebrospinal Fluid from Ataxia-Telangiectasia (A-T) Patients Using a LC/MS-Based Label-Free Protein Quantification Technology | International journal of proteomics |
| 21105691 | 2010-12-20 | Substitution of the terminal chloride ligands of [Re(6)S(8)Cl(6)](4-) with triethylphosphine: photophysical and electrochemical properties of a new series of [Re(6)S(8)](2+) based clusters | Inorganic chemistry |
