Triphenyl Borate

Product Information

Molecular Formula:
C18H15O3B
Molecular Weight:
290.12
Description
Catalyst involved in: Multicomponent aziridination of aldehydes; Hetero-Diels-Alder reactions and Mukaiyama aldol condensation; Cross-metathesis of alkenes with 3-nitropropene; Asymmetric Claisen rearrangement of unactivated allyl vinyl ethers; Ethoxylation; Asymmetric aziridination of imines.
Synonyms
triphenyl borate; triphenyl borate
IUPAC Name
triphenyl borate
Canonical SMILES
B(OC1=CC=CC=C1)(OC2=CC=CC=C2)OC3=CC=CC=C3
InChI
InChI=1S/C18H15BO3/c1-4-10-16(11-5-1)20-19(21-17-12-6-2-7-13-17)22-18-14-8-3-9-15-18/h1-15H
InChI Key
MDCWDBMBZLORER-UHFFFAOYSA-N
Boiling Point
343.2 °C at 760 mmHg
Melting Point
98-101 °C (lit.)
Flash Point
Not applicable
Purity
≥ 97 %
Density
1.134 g/cm3
Appearance
Solid
Storage
Inert atmosphere, 2-8 °C
LogP
4.20830

Safety Information

Hazards
H301 + H311 + H331 - H318
Precautionary Statement
P261, P264, P270, P271, P280, P301+P310, P302+P352, P304+P340, P305+P351+P338, P310, P311, P312, P321, P322, P330, P361, P363, P403+P233, P405, and P501
Signal Word
Danger

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
6
Exact Mass
290.1114245 g/mol
Monoisotopic Mass
290.1114245 g/mol
Topological Polar Surface Area
27.7Ų
Heavy Atom Count
22
Formal Charge
0
Complexity
247
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
JP-2022037181-A A method for producing a chemically amplified photosensitive composition, a photosensitive dry film, and a method for producing a patterned resist film. 2021-12-22
CN-114057995-A Underfill material and preparation method and application thereof 2021-12-16
CN-113896694-A Polyfunctional group hybrid epoxy compound and photo-thermal dual-curing resin composition as well as preparation method and application thereof 2021-11-16
CN-113831383-A Preparation method of abiraterone 2021-11-03
CN-113881210-A High-fluidity transparent polycarbonate material and preparation method thereof 2021-10-27
CN-113788935-A Epoxy resin composition and preparation method and application thereof 2021-10-22
CN-113788936-A Light/heat dual-curing resin composition and preparation method and application thereof 2021-10-22
CN-113860980-A Method for preparing arylamine compound by photoinduced reduction C-N coupling reaction 2021-10-11
CN-113652186-A Photo-thermal dual-curing resin composition and preparation method and application thereof 2021-09-29
CN-113736403-A Single-component heat-resistant epoxy resin composition and preparation method and application thereof 2021-09-29

Literatures

PMID Publication Date Title Journal
22253063 2012-03-01 First isolation of disubstituted cis-5,6-dihydro-1,10-phenanthrolines. Lipase-mediated resolution of cis- and trans-phenoxy alcohol isomers and assignment of absolute stereochemistry via CD and NMR spectroscopy Chirality
19921061 2009-12-14 Synthesis and characterization of neutral iron(II) and ruthenium(II) complexes with the isocyanotriphenylborate ligand Dalton transactions (Cambridge, England : 2003)
18306265 2008-01-01 Catalytic asymmetric aziridination with borate catalysts derived from VANOL and VAPOL ligands: scope and mechanistic studies Chemistry (Weinheim an der Bergstrasse, Germany)
17497860 2007-06-06 Direct access to N-H-aziridines from asymmetric catalytic aziridination with borate catalysts derived from vaulted binaphthol and vaulted biphenanthrol ligands Journal of the American Chemical Society
11700110 2001-11-15 An efficient synthesis of (-)-chloramphenicol via asymmetric catalytic aziridination: a comparison of catalysts prepared from triphenylborate and various linear and vaulted biaryls Organic letters
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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