Diphenyliodonium hexafluorophosphate

Product Information

Molecular Formula:
C12H10F6IP
Molecular Weight:
426.08
Description
Cationic photoinitiator. Photoacid generator.
Synonyms
DPIHFP
IUPAC Name
diphenyliodaniumhexafluorophosphate
Canonical SMILES
F[P-](F)(F)(F)(F)F.[I+](c1ccccc1)c2ccccc2
InChI
InChI=1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-121-7(2,3,4,5)6/h1-10H/q+1-1
InChI Key
DSSRLRJACJENEU-UHFFFAOYSA-N
Melting Point
142 °C(dec.)
Purity
≥98%
Appearance
White to Almost white powder to crystal
Application
Cationic photoinitiator.

Safety Information

Hazards
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Precautionary Statement
P264:
Wash thoroughly after handling.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:
IF ON SKIN:
Wash with plenty of soap and water.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P362+P364:
Take off contaminated clothing. [As modified by IV ATP].
And wash it before reuse. [Added by IV ATP].
Signal Word
Danger

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
7
Rotatable Bond Count
2
Exact Mass
425.94690 g/mol
Monoisotopic Mass
425.94690 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
20
Formal Charge
0
Complexity
179
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
JP-2022037181-A A method for producing a chemically amplified photosensitive composition, a photosensitive dry film, and a method for producing a patterned resist film. 2021-12-22
CN-114133467-A Unsaturated esterified monomer and ester low-bleeding polycarboxylate superplasticizer and preparation method thereof 2021-12-16
CN-113968945-A Antibacterial polyurethane composite resin and preparation method and application thereof 2021-12-15
CN-114045020-A Chopped fiber reinforced photosensitive resin for 3D printing and preparation method thereof 2021-11-17
CN-113831329-A Crosslinking agent and preparation method and application thereof 2021-11-05
CN-113912772-A Thermosensitive resin, environment-friendly thermosensitive plate and preparation method thereof 2021-11-05
CN-113942289-A Imageable composition for photosensitive negative-working lithographic printing plate and plate making method thereof 2021-10-26
CN-113954502-A Photosensitive negative-working lithographic printing plate precursor and method for making lithographic printing plate by using the same 2021-10-26
CN-114011453-A In-situ photoinduction self-assembly synthesis method of high-dispersion Cu @ SBA-15 2021-10-26
CN-113929900-A Polyether high polymer and anti-reflection coating solution and preparation method thereof 2021-10-15

Literatures

PMID Publication Date Title Journal
33577942 2021-04-01 Involvement of NADPH oxidase in patulin-induced oxidative damage and cytotoxicity in HEK293 cells Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association
23083514 2012-12-01 Polymerization kinetics and reactivity of alternative initiators systems for use in light-activated dental resins Dental materials : official publication of the Academy of Dental Materials
22854914 2012-09-18 Base- and metal-free C-H direct arylations of naphthalene and other unbiased arenes with diaryliodonium salts Chemical communications (Cambridge, England)
22488067 2012-04-01 Effect of thymol or diphenyliodonium chloride on performance, gut fermentation characteristics, and campylobacter colonization in growing swine Journal of food protection
22340895 2012-02-16 Naloxone inhibits immune cell function by suppressing superoxide production through a direct interaction with gp91phox subunit of NADPH oxidase Journal of neuroinflammation
22240163 2012-01-12 NADPH oxidase and reactive oxygen species contribute to alcohol-induced microglial activation and neurodegeneration Journal of neuroinflammation
22493722 2012-01-01 Reactive oxygen species facilitate translocation of hormone sensitive lipase to the lipid droplet during lipolysis in human differentiated adipocytes PloS one
22722757 2012-01-01 Role of reactive oxygen species in transforming growth factor beta1-induced alpha smooth-muscle actin and collagen production in nasal polyp-derived fibroblasts International archives of allergy and immunology
22768082 2012-01-01 Myocardial autophagy after severe burn in rats PloS one
21848264 2011-09-07 Enantioselective α-arylation of N-acyloxazolidinones with copper(II)-bisoxazoline catalysts and diaryliodonium salts Journal of the American Chemical Society
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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