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[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Inquiry

Molecular Formula:

C26H24Cl2NiP2

Molecular Weight:

528.02

CAS Number:

14647-23-5

Catalog Number:

14647-23-5

Product Information

Molecular Formula:

C26H24Cl2NiP2

Molecular Weight:

528.02

Description

Reactant involved in: Kumada catalyst-transfer polycondensation; Oxidation of carboranyl phosphine ligands; Synthesis of nickel-iron dithiolato hydrides; Ullmann reactions - homocoupling reactionsCo-catalyst for hydroformylation of alcohols for the synthesis of quaternary carbon centersCatalyst for Wacker-type intramolecular aerobic oxidative amination of alkenes.

Synonyms

1,2-Ethylenebis(diphenylphosphine)nickel dichloride; Nickel 1,2-Bis(diphenylphosphino)ethane dichloride; [1,2-Bis(diphenylphosphino)ethane]nickel(II) chloride; dppeNiCl2; Nickel(2+) ion [2-(diphenylphosphanyl)ethyl]diphenylphosphane dichloride; Dichloro[1,2-bis(diphenylphosphino)ethane]nickel(II)

IUPAC Name

2-diphenylphosphanylethyl(diphenyl)phosphane;nickel(2+);dichloride

Canonical SMILES

C1=CC=C(C=C1)P(CCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.[Cl-].[Cl-].[Ni+2]

InChI

InChI=1S/C26H24P2.2ClH.Ni/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26;;;/h1-20H,21-22H2;2*1H;/q;;;+2/p-2

InChI Key

XXECWTBMGGXMKP-UHFFFAOYSA-L

Melting Point

263-265 ℃

Purity

> 96.0 % (T)

Appearance

Orange to amber to dark red powder to crystal

Storage

Refrigerator

Safety Information

Hazards

H302 H312 H315 H319 H332 H334 H335 H350

Precautionary Statement

P201 P261 P280 P305+P351+P338 P308+P313

Signal Word

Danger

Computed Properties

Hydrogen Bond Donor Count

Hydrogen Bond Acceptor Count

Rotatable Bond Count

Exact Mass

526.008372 g/mol

Monoisotopic Mass

526.008372 g/mol

Topological Polar Surface Area

0Å²

Heavy Atom Count

Formal Charge

Complexity

336

Isotope Atom Count

Defined Atom Stereocenter Count

Undefined Atom Stereocenter Count

Defined Bond Stereocenter Count

Undefined Bond Stereocenter Count

Covalently-Bonded Unit Count

Compound Is Canonicalized

Yes

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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[1,2-Bis(diphenylphosphino)ethane]dichloronickel(II)

Product Information

Safety Information

Computed Properties

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