1,3-Bis(diphenylphosphino)propane nickel(II) chloride
Product Information
Molecular Formula
C27H26Cl2NiP2
Molecular Weight
542.04
Description
1,3-Bis(diphenylphosphino)propane nickel(II) chloride is used as an effective catalyst for Kumada coupling and Suzuki reactions.
Synonyms
Ni(dppp)Cl2; 1,3-Bis(diphenylphosphino)propane nickel (II) chloride; [1,3-Bis(diphenylphosphino)propane]dichloronickel(II)
IUPAC Name
dichloronickel;3-diphenylphosphanylpropyl(diphenyl)phosphane
SMILES
C1=CC=C(C=C1)P(CCCP(C2=CC=CC=C2)C3=CC=CC=C3)C4=CC=CC=C4.Cl[Ni]Cl
InChI
InChI=1S/C27H26P2.2ClH.Ni/c1-5-14-24(15-6-1)28(25-16-7-2-8-17-25)22-13-23-29(26-18-9-3-10-19-26)27-20-11-4-12-21-27;;;/h1-12,14-21H,13,22-23H2;2*1H;/q;;;+2/p-2
InChI Key
ZBQUMMFUJLOTQC-UHFFFAOYSA-L
Melting Point
213°C (dec.)(lit.)
Purity
> 98.0 % (T)
Appearance
Orange to brown to dark red powder to crystal
Safety Information
Hazards
H315 H317 H319 H334 H335 H350
Precautionary Statement
P201 P261 P280 P305+P351+P338 P308+P313
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
8
Exact Mass
540.024022 g/mol
Monoisotopic Mass
540.024022 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
32
Formal Charge
0
Complexity
353
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114085362-A | Preparation method and application technical field of polymer donor material containing multi-element aromatic ring thieno-thiophene diketone | 2021-12-06 |
| CN-114015245-A | Stable rubber powder polymer composite modified asphalt and mixture | 2021-10-20 |
| CN-113831514-A | End-capped polymer and preparation method and application thereof | 2021-09-28 |
| CN-113354578-A | Synthetic method of 2-isopropyl-3-amino-4-methylpyridine | 2021-07-12 |
| CN-113278003-A | Material with deuterated anthracene spirofluorene cyclic ether as main body and application | 2021-05-25 |
| CN-112961025-A | Synthesis method, derivation method and derivatives of non-benzene polycyclic aromatic hydrocarbon APD | 2021-03-24 |
| CN-112939728-A | Preparation method of frainer intermediate 1, 3-dichloro-alpha- (trifluoromethyl) styrene | 2021-02-03 |
| CN-112778502-A | Viscoelastic fluorescent conjugated polymer and preparation method thereof | 2020-12-30 |
| WO-2022032026-A1 | Compounds for targeted degradation of ret | 2020-08-05 |
| JP-2022024744-A | Composition and light emitting device | 2020-07-28 |
