2-(Diphenylphosphino)benzaldehyde

Product Information

Molecular Formula:
C19H15OP
Molecular Weight:
290.30
Description
2-(Diphenylphosphino)benzaldehyde (CAS# 50777-76-9) is a useful research chemical.
Synonyms
2-diphenylphosphanylbenzaldehyde
IUPAC Name
2-diphenylphosphanylbenzaldehyde
Canonical SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C=O
InChI
InChI=1S/C19H15OP/c20-15-16-9-7-8-14-19(16)21(17-10-3-1-4-11-17)18-12-5-2-6-13-18/h1-15H
InChI Key
DRCPJRZHAJMWOU-UHFFFAOYSA-N
Boiling Point
417.444 °C at 760 mmHg
Melting Point
112-115 °C
Flash Point
Not applicable
Purity
95 %
Appearance
Yellow powder or crystals
LogP
3.25730

Safety Information

Hazards
H315 - H319 - H335
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning

Computed Properties

XLogP3
4.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
1
Rotatable Bond Count
4
Exact Mass
290.086052095 g/mol
Monoisotopic Mass
290.086052095 g/mol
Topological Polar Surface Area
17.1Ų
Heavy Atom Count
21
Formal Charge
0
Complexity
300
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114014891-A Purine ring modified fluorescent probe and application thereof in cobalt ion detection 2021-11-25
CN-114085200-A Method for preparing 2, 5-furandicarboxylic acid by using 2-furancarboxylic acid as raw material through one-pot method 2021-11-15
CN-114031494-A Method for preparing carboxylic acid by catalyzing reaction of unsaturated hydrocarbon and formic acid by using catalyst containing noble metal compound 2021-11-01
CN-113651856-A Phosphine zwitterionic complex and ligand, preparation method and application thereof 2021-08-25
CN-113398999-A Catalyst for hydroboration reaction and preparation and application methods thereof 2021-07-27
CN-112679541-A Preparation method and application of metal organic ternary cyclic compound 2020-12-28
CN-112608340-A Tetradentate nitrogen phosphine ligand and preparation method and application thereof 2020-11-25
CN-111848321-A Chiral aminated sulfoxide and preparation method thereof 2020-06-12
CN-113797977-A Ruthenium catalyst and application thereof 2020-06-12
JP-2021161333-A Polycarbonate resin composition and its molded product 2020-04-02

Literatures

PMID Publication Date Title Journal
22240994 2012-03-14 Synthesis of the phosphino-fullerene PPh2(o-C6H4)(CH2NMeCH)C60 and its function as an η1-P or η3-P,C2 ligand Dalton transactions (Cambridge, England : 2003)
22324763 2012-03-14 Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands Journal of the American Chemical Society
21989479 2011-12-14 Aldimines generated from aza-Wittig reaction between bis(iminophosphoranes) derived from 1,1'-diazidoferrocene and aromatic or heteroaromatic aldehydes: electrochemical and optical behaviour towards metal cations Dalton transactions (Cambridge, England : 2003)
22219850 2011-11-01 Chlorido{N-[2-(diphenyl-phosphan-yl)benz-yl]-1-(pyridin-2-yl)methanamine-κP}gold(I) Acta crystallographica. Section E, Structure reports online
21887831 2011-10-10 Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy Chemistry (Weinheim an der Bergstrasse, Germany)
21898610 2011-10-10 Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines Chemistry (Weinheim an der Bergstrasse, Germany)
21579327 2010-05-22 Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl)ethanamine-κN,P}methylpalladium(II) dichloromethane hemisolvate Acta crystallographica. Section E, Structure reports online
21579222 2010-04-28 Diphen-yl[2-(2-pyridylamino-meth-yl)phen-yl]phosphine oxide Acta crystallographica. Section E, Structure reports online
19719180 2009-08-06 Total synthesis of (+)-bourgeanic acid utilizing o-DPPB-directed allylic substitution Organic letters
19452073 2009-06-07 New hydridoirida-beta-diketones derived from 8-quinoline-carbaldehyde and o-(diphenylphosphino)benzaldehyde Dalton transactions (Cambridge, England : 2003)
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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