Home
Products
Reagents for Polymerization
Polymerization Catalysts
Cross-Coupling Reaction Catalyst
cis-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](2-methylphenyl)nickel(II) chloride

cis-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](2-methylphenyl)nickel(II) chloride

Inquiry

Molecular Formula:

C51H39ClNiP2

Molecular Weight:

807.95

CAS Number:

1594113-05-9

Catalog Number:

1594113-05-9

Product Information

Molecular Formula:

C51H39ClNiP2

Molecular Weight:

807.95

Description

The following Ni-complex is an air-stable precatalyst for various Ni-catalyzed reactions which normally require Ni(cod)2, however, this precatalyst will not require any glovebox or schlenk techniques that must be followed with Ni(cod)2. Rates are enhanced and selectivity is maintained when compared to the same reaction with Ni(cod)2.

Synonyms

cis-((S)-BINAP)Ni(o-tolyl)Cl

IUPAC Name

chloronickel[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphanemethylbenzene

Canonical SMILES

CC1=CC=CC=[C-]1.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.Cl[Ni]

InChI

InChI=1S/C44H32P2.C7H7.ClH.Ni/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-381-7-5-3-2-4-6-7/h1-32H2-5H,1H31H/q-1+1/p-1

InChI Key

BDNFRUZOTUFTCF-UHFFFAOYSA-M

Melting Point

>300 °C

Flash Point

Not applicable

Computed Properties

Hydrogen Bond Donor Count

Hydrogen Bond Acceptor Count

Rotatable Bond Count

Exact Mass

806.156895 g/mol

Monoisotopic Mass

806.156895 g/mol

Topological Polar Surface Area

0Å²

Heavy Atom Count

Formal Charge

-1

Complexity

942

Isotope Atom Count

Defined Atom Stereocenter Count

Undefined Atom Stereocenter Count

Defined Bond Stereocenter Count

Undefined Bond Stereocenter Count

Covalently-Bonded Unit Count

Compound Is Canonicalized

Yes

The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

Mass

Concentration

Volume

Molecular Weight *

Calculate

The dilution calculator equation

Concentration _(start) × Volume _(start) = Concentration _(final) × Volume _(final)

This equation is commonly abbreviated as: C₁V₁ = C₂V₂

Concentration _(start)

Volume _(start)

Concentration _(final)

Volume _(final)

Calculate

cis-[2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl](2-methylphenyl)nickel(II) chloride

Product Information

Computed Properties

Related Products