Ethyldiphenylphosphine

Product Information

Molecular Formula:
C14H15P
Molecular Weight:
214.24
Description
Catalyst for: Three component coupling reactions of arylaldehydes with Me vinyl ketone and phthalimide; Regio- and stereoselective hydroalkynylation of methylenecyclopropanes; Synthesis of oxazolidines, thiazolidines, pyrrolidines, and indoles; Dimer to monomer conversion; Tandem Morita-Baylis-Hillman/Michael addition reactions; Platinum-catalyzed cyclization; Regioselective and stereoselective [3+2] cycloaddition; Platinum-catalyzed intermolecular hydroamination; Hydroformylation reactions.
Synonyms
ethyl(diphenyl)phosphine; ethyl(diphenyl)phosphane
IUPAC Name
ethyl(diphenyl)phosphane
Canonical SMILES
CCP(C1=CC=CC=C1)C2=CC=CC=C2
InChI
InChI=1S/C14H15P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h3-12H,2H2,1H3
InChI Key
WUOIAOOSKMHJOV-UHFFFAOYSA-N
Boiling Point
293 °C (lit.)
Flash Point
230.0 °F - closed cup
Purity
98 %
Density
1.048 g/mL at 25 °C (lit.)
Refractive Index
n20/D 1.614 (lit.)
LogP
3.13920

Safety Information

Hazards
H302 - H315 - H319 - H335
Precautionary Statement
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning

Computed Properties

XLogP3
3.4
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
3
Exact Mass
214.091137476 g/mol
Monoisotopic Mass
214.091137476 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
148
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114105817-A Method for continuously preparing adiponitrile by hydrocyanating 1, 3-butadiene 2021-12-10
CN-113582936-A Synthesis method of palladium-catalyzed N-aryl benzotriazole derivative 2021-08-11
CN-113461539-A Method for preparing organic diamine from amino nitrile organic matter 2021-08-02
CN-113441166-A Nitrogen-phosphorus co-doped carbon-based cobalt catalyst, preparation method thereof and synthesis method of saturated aliphatic primary amine 2021-08-02
CN-113385205-A Metal phosphide catalyst for heterogeneous hydroformylation reaction 2021-07-16
CN-113214119-A Selective addition method of dienamine and phenylboronic acid controlled by small steric hindrance 2021-03-22
JP-2021080483-A Complex 2021-03-04
CN-112939917-A Preparation method of flavonoid compound 2021-02-08
CN-112387280-A Method for preparing isopentenal by oxidizing enol 2020-11-26
CN-112321557-A Preparation method of Jiale musk 2020-09-14

Literatures

PMID Publication Date Title Journal
22446986 2012-03-02 Tandem three-component reactions of aldehyde, alkyl acrylate, and dialkylmalonate catalyzed by ethyl diphenylphosphine Molecules (Basel, Switzerland)
21522535 2010-12-24 Azido-[1,2-bis-(diphenyl-phosphan-yl)ethane-κP,P'](η-inden-yl)ruthenium(II) Acta crystallographica. Section E, Structure reports online
20976326 2010-12-14 Dinuclear platinum(II) 4,6-diphenyl-2,2'-bipyridine complexes tethered by a rigid bridging ligand: synthesis and photophysics in solution and in LB film Dalton transactions (Cambridge, England : 2003)
20836513 2010-10-18 Facile determination of the spectra of unstable electrode products using simultaneous fiber-optic chronoabsorptometry and chronoamperometry Inorganic chemistry
21587711 2010-06-16 Trichloridobis(ethyl-diphenyl-phosphine)(tetra-hydro-furan)-molybdenum(III) Acta crystallographica. Section E, Structure reports online
21202265 2008-04-30 Chlorido(ethyl-diphenyl-phosphine-κP)(1-pyrrolidinecarbodithio-ato-κS,S')nickel(II) Acta crystallographica. Section E, Structure reports online
18190207 2008-01-07 Scanning tunneling microscopy studies of pulse deposition of dinuclear organometallic molecules on Au(111) The Journal of chemical physics
17304612 2007-01-01 Comparative experimental and EXAFS studies in the Mizoroki-Heck reaction with heteroatom-functionalised N-heterocyclic carbene palladium catalysts Chemistry (Weinheim an der Bergstrasse, Germany)
16129706 2005-09-05 Type I interferons act directly on CD8 T cells to allow clonal expansion and memory formation in response to viral infection The Journal of experimental medicine
16161315 2005-01-01 [Regulation of glycemia, just where and when in the aged?] Journees annuelles de diabetologie de l'Hotel-Dieu
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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