Methyl trimethylsilyl dimethylketene acetal

Product Information

Molecular Formula:
C8H18O2Si
Molecular Weight:
174.31
Description
Methyl trimethylsilyl dimethylketene acetal (CAS# 31469-15-5) is useful in the synthesis of organic compounds such as 1,​1'-​Bis[1-​(1-​methoxycarbonyl-​1-​methyl-​ethyl)​-​3-​butenyl] Ferrocene Monome, Alkylbismuths and N-​Tosyl-α,​β-​dehydroamino Esters.
Synonyms
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
IUPAC Name
(1-methoxy-2-methylprop-1-enoxy)-trimethylsilane
Canonical SMILES
CC(=C(OC)O[Si](C)(C)C)C
InChI
InChI=1S/C8H18O2Si/c1-7(2)8(9-3)10-11(4,5)6/h1-6H3
InChI Key
JNOGVQJEBGEKMG-UHFFFAOYSA-N
Boiling Point
52 ℃ / 22 mmHg
Flash Point
30 °C
Purity
> 95.0 % (GC)
Density
0.858 g/cm3
Appearance
Colorless liquid
Refractive Index
1.42
LogP
2.73570

Safety Information

Hazards
H315 H319 H226
Precautionary Statement
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word
Warning

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
3
Exact Mass
174.107606347 g/mol
Monoisotopic Mass
174.107606347 g/mol
Topological Polar Surface Area
18.5Ų
Heavy Atom Count
11
Formal Charge
0
Complexity
152
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
JP-2022036986-A Infrared light transmission type composition 2021-11-22
CN-113956422-A Silane modified acrylate polymer, preparation method and application thereof, acrylate polymer coating and application thereof 2021-11-12
CN-114057935-A Acrylic ester polymer, preparation method and application thereof, acrylic ester polymer coating and application thereof 2021-11-12
CN-113717078-A Method for co-producing stabilized tar by TDI and utilization method of stabilized tar 2021-09-17
CZ-35202-U1 Polymer composite comprising a polymer matrix and carbon nanostructures with a non-covalently bound dispersant 2021-03-23
CN-112836740-A Markov-based open composite domain-based method for improving model domain adaptivity 2021-01-29
CN-112836740-B Markov-based open composite domain-based method for improving model domain adaptivity 2021-01-29
CN-112661693-A Preparation method of fexofenadine 2021-01-27
JP-2022039341-A Coloring compositions, color filters, liquid crystal displays, and solid-state image sensors. 2020-08-28
JP-2022028533-A Curable resin composition and its use 2020-08-03

Literatures

PMID Publication Date Title Journal
19795856 2009-11-06 P(PhCH2NCH2CH2)3N catalysis of Mukaiyama aldol reactions of aliphatic, aromatic, and heterocyclic aldehydes and trifluoromethyl phenyl ketone The Journal of organic chemistry
17154468 2006-12-01 Amphiphilic model conetworks based on cross-linked star copolymers of benzyl methacrylate and 2-(dimethylamino)ethyl methacrylate: synthesis, characterization, and DNA adsorption studies Biomacromolecules
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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