Tricyclohexyl phosphine
| Catalog Number | Size | Price | Stock | Quantity |
|---|---|---|---|---|
| BPM-064489 | 100 g | $199 | In stock |
Product Information
Molecular Formula
C18H33P
Molecular Weight
280.43
Description
Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
Synonyms
Phosphine, tricyclohexyl-
IUPAC Name
tricyclohexylphosphane
SMILES
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InChI
InChI=1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
InChI Key
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Boiling Point
383.4 °C at 760 mmHg
Melting Point
77-83 °C
Purity
95 %
Density
0.909 g/mL at 25 °C
Appearance
White to off-white solid
Storage
-20 °C
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P302 + P352 - P305 + P351 + P338
Signal Word
Danger
Computed Properties
XLogP3
5.4
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
3
Exact Mass
280.231988050 g/mol
Monoisotopic Mass
280.231988050 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
19
Formal Charge
0
Complexity
202
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114163618-A | Narrow-bandgap polymer based on benzodithiadiazole or thiadiazole quinoxaline, and preparation method and application thereof | 2022-01-27 |
| CN-114031475-A | Bromine simple substance-promoted extremely-low-dose palladium-catalyzed water-phase Suzuki coupling reaction method | 2021-12-24 |
| CN-114163465-A | Synthesis method of alkenyl borate compound | 2021-12-24 |
| JP-2022040133-A | A photosensitive coloring composition for a color filter for a solid-state image sensor, a color filter, and a solid-state image sensor using the same. | 2021-12-15 |
| CN-113980044-A | Preparation method of Ir-O-P type catalyst diboronic acid/ester compound | 2021-12-03 |
| CN-114057824-A | Tripterine derivative and preparation method and application thereof | 2021-11-25 |
| CN-113943311-A | Preparation and application of novel non-fullerene micromolecule | 2021-11-22 |
| CN-114058020-A | Preparation method and application of quaternary phosphonium salt | 2021-11-20 |
| CN-113816917-A | Preparation method of wibeled intermediate | 2021-11-19 |
| CN-113816917-B | Preparation method of wibeled intermediate | 2021-11-19 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 23035731 | 2012-10-16 | Filling gaps in asymmetric hydrogenation methods for acyclic stereocontrol: application to chirons for polyketide-derived natural products | Accounts of chemical research |
| 22985393 | 2012-09-26 | Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy esters | Journal of the American Chemical Society |
| 22092010 | 2011-12-19 | Pyridazine based scorpionate ligand in a copper boratrane compound | Inorganic chemistry |
| 21999582 | 2011-11-07 | Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes | Inorganic chemistry |
| 21724304 | 2011-09-01 | Synthesis, characterization and anticancer studies of mixed ligand dithiocarbamate palladium(II) complexes | European journal of medicinal chemistry |
| 21761078 | 2011-08-28 | Cytotoxic gold(I)-bearing dendrimers from alkyne precursors | Dalton transactions (Cambridge, England : 2003) |
| 21775812 | 2011-08-01 | Deducing chemical structure from crystallographically determined atomic coordinates | Acta crystallographica. Section B, Structural science |
| 21534543 | 2011-06-03 | Syntheses of α-pyrones using gold-catalyzed coupling reactions | Organic letters |
| 21387425 | 2011-04-04 | Substantiating the influence of pore surface functionalities on the stability of Grubbs catalyst in mesoporous SBA-15 silica | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 21302930 | 2011-03-10 | 8-Azatetracyclines: synthesis and evaluation of a novel class of tetracycline antibacterial agents | Journal of medicinal chemistry |
