Tricyclohexyl phosphine

Catalog Number Size Price Stock Quantity
BPM-064489 100 g $199 In stock
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Product Information

Molecular Formula
C18H33P
Molecular Weight
280.43
Description
Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds.
Synonyms
Phosphine, tricyclohexyl-
IUPAC Name
tricyclohexylphosphane
Canonical SMILES
C1CCC(CC1)P(C2CCCCC2)C3CCCCC3
InChI
InChI=1S/C18H33P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h16-18H,1-15H2
InChI Key
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Boiling Point
383.4 °C at 760 mmHg
Melting Point
77-83 °C
Purity
95 %
Density
0.909 g/mL at 25 °C
Appearance
White to off-white solid
Storage
-20 °C

Safety Information

Hazards
H315 - H319 - H335
Precautionary Statement
P302 + P352 - P305 + P351 + P338
Signal Word
Danger

Computed Properties

XLogP3
5.4
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
3
Exact Mass
280.231988050 g/mol
Monoisotopic Mass
280.231988050 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
19
Formal Charge
0
Complexity
202
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114163618-A Narrow-bandgap polymer based on benzodithiadiazole or thiadiazole quinoxaline, and preparation method and application thereof 2022-01-27
CN-114031475-A Bromine simple substance-promoted extremely-low-dose palladium-catalyzed water-phase Suzuki coupling reaction method 2021-12-24
CN-114163465-A Synthesis method of alkenyl borate compound 2021-12-24
JP-2022040133-A A photosensitive coloring composition for a color filter for a solid-state image sensor, a color filter, and a solid-state image sensor using the same. 2021-12-15
CN-113980044-A Preparation method of Ir-O-P type catalyst diboronic acid/ester compound 2021-12-03
CN-114057824-A Tripterine derivative and preparation method and application thereof 2021-11-25
CN-113943311-A Preparation and application of novel non-fullerene micromolecule 2021-11-22
CN-114058020-A Preparation method and application of quaternary phosphonium salt 2021-11-20
CN-113816917-A Preparation method of wibeled intermediate 2021-11-19
CN-113816917-B Preparation method of wibeled intermediate 2021-11-19

Literatures

PMID Publication Date Title Journal
23035731 2012-10-16 Filling gaps in asymmetric hydrogenation methods for acyclic stereocontrol: application to chirons for polyketide-derived natural products Accounts of chemical research
22985393 2012-09-26 Direct, redox-neutral prenylation and geranylation of secondary carbinol C-H bonds: C4-regioselectivity in ruthenium-catalyzed C-C couplings of dienes to α-hydroxy esters Journal of the American Chemical Society
22092010 2011-12-19 Pyridazine based scorpionate ligand in a copper boratrane compound Inorganic chemistry
21999582 2011-11-07 Synthesis, antimicrobial and antiproliferative activity of novel silver(I) tris(pyrazolyl)methanesulfonate and 1,3,5-triaza-7-phosphadamantane complexes Inorganic chemistry
21724304 2011-09-01 Synthesis, characterization and anticancer studies of mixed ligand dithiocarbamate palladium(II) complexes European journal of medicinal chemistry
21761078 2011-08-28 Cytotoxic gold(I)-bearing dendrimers from alkyne precursors Dalton transactions (Cambridge, England : 2003)
21775812 2011-08-01 Deducing chemical structure from crystallographically determined atomic coordinates Acta crystallographica. Section B, Structural science
21534543 2011-06-03 Syntheses of α-pyrones using gold-catalyzed coupling reactions Organic letters
21387425 2011-04-04 Substantiating the influence of pore surface functionalities on the stability of Grubbs catalyst in mesoporous SBA-15 silica Chemistry (Weinheim an der Bergstrasse, Germany)
21302930 2011-03-10 8-Azatetracyclines: synthesis and evaluation of a novel class of tetracycline antibacterial agents Journal of medicinal chemistry
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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