Tricyclohexylphosphonium Tetrafluoroborate

Product Information

Molecular Formula:
C18H34F4PB
Molecular Weight:
368.24
Description
Tricyclohexylphosphine tetrafluoroborate may be used in the following processes: As a ligand for preparing C-homoaporphine alkaloids via microwave-assisted direct-arylation; To synthesize poly-[9,9-bis(3-propylamide-2-methylpropyl sulfonic acid) fluorene]-co-(4,4'-diphenyl) (PFDBSO3H), which can be employed as a template and doping agent for enhancing the conductivity of poly(3,4-ethylenedioxythiophene) (PEDOT) films; To improve the reactivity of palladium-catalyzed Suzuki-Miyaura cross-coupling reaction between MIDA boronates and less activated alkenyl tosylates. Used with Ru(cod)Cl dimer to catalyze the dehydrogenative coupling of alcohols and amines to form amide bonds.
Synonyms
tricyclohexylphosphonium;tetrafluoroborate; tricyclohexylphosphanium;tetrafluoroborate
IUPAC Name
tricyclohexylphosphanium;tetrafluoroborate
Canonical SMILES
[B-](F)(F)(F)F.C1CCC(CC1)[PH+](C2CCCCC2)C3CCCCC3
InChI
InChI=1S/C18H33P.BF4/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;2-1(3,4)5/h16-18H,1-15H2;/q;-1/p+1
InChI Key
MYSMMEUXKHJYKH-UHFFFAOYSA-O
Melting Point
164 °C (lit.)
Flash Point
Not applicable
Purity
97 %
LogP
7.49870

Safety Information

Precautionary Statement
P260, P261, P264, P270, P271, P280, P301+P312, P301+P330+P331, P302+P352, P303+P361+P353, P304+P312, P304+P340, P305+P351+P338, P310, P312, P321, P322, P330, P332+P313, P337+P313, P362, P363, P403+P233, P405, and P501
Signal Word
Danger

Computed Properties

Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
5
Rotatable Bond Count
3
Exact Mass
368.2427309 g/mol
Monoisotopic Mass
368.2427309 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
24
Formal Charge
0
Complexity
221
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
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CN-114044733-A Method for efficiently synthesizing 2-bromo-9,9-diphenylfluorene by metal catalysis 2021-11-28
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CN-113991044-A Green organic electroluminescent device and display device including the same 2021-10-29
CN-113735870-A Compound containing nitrogen and hetero-structure and application thereof 2021-09-15
CN-113529110-A Electrochemical-promoted substituted aromatic meta-nitration method 2021-07-08
CN-113493455-A Organic compound, electronic element, and electronic device 2021-07-05
CN-113429413-A Compound and device containing benzofuran carbazole derivative and dibenzofuran 2021-06-28
CN-113387819-A Phenanthrene compound, preparation method and application thereof, and organic electroluminescent device 2021-06-28
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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