TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE

Product Information

Molecular Formula:
C27H33O9P
Molecular Weight:
532.52
Description
Highly basic arylphosphine.
Synonyms
Phosphine, tris(2,4,6-trimethoxyphenyl)-; TRIS(2,4,6-TRIMETHOXYPHENYL)PHOSPHINE; TTMPP; Tris(2,4,6-trimethoxyphenyl)phosphine,min.97%; Tris(2,4,6-trimethoxyphenyl)phosphine, min. 97%; Tri(2,4,6-trimethoxyphenyl)phosphine
IUPAC Name
tris(2,4,6-trimethoxyphenyl)phosphane
Canonical SMILES
COC1=CC(=C(C(=C1)OC)P(C2=C(C=C(C=C2OC)OC)OC)C3=C(C=C(C=C3OC)OC)OC)OC
InChI
InChI=1S/C27H33O9P/c1-28-16-10-19(31-4)25(20(11-16)32-5)37(26-21(33-6)12-17(29-2)13-22(26)34-7)27-23(35-8)14-18(30-3)15-24(27)36-9/h10-15H,1-9H3
InChI Key
JQKHNBQZGUKYPX-UHFFFAOYSA-N
Melting Point
155-160 °C (lit.)
Flash Point
Not applicable

Computed Properties

XLogP3
4.3
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
9
Rotatable Bond Count
12
Exact Mass
532.18621962 g/mol
Monoisotopic Mass
532.18621962 g/mol
Topological Polar Surface Area
83.1Ų
Heavy Atom Count
37
Formal Charge
0
Complexity
530
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-112876658-A Dithienopyrrole-based polymer and preparation method and application thereof 2021-03-02
CN-112661939-A Polymer, preparation method and application thereof 2020-12-17
CN-111808041-A Difluoroalkyl aryl oxazolidinone compound and preparation method thereof 2020-08-17
JP-2022028533-A Curable resin composition and its use 2020-08-03
CN-111825715-A Synthesis method of triphenylphosphine derivative tri- (R-phenyl) phosphine 2020-07-16
JP-2021183314-A Emulsifying composition containing emulsifier and emulsifier 2020-05-22
JP-2021183676-A Production method of diblock type copolymer, diblock type copolymer and use of diblock type copolymer 2020-05-22
WO-2021235266-A1 Diblock copolymer, method for producing diblock copolymer, and use of diblock copolymer 2020-05-22
WO-2021235274-A1 Emulsifier and emulsion composition containing same 2020-05-22
CN-111574707-A Modified polyphenyl ether, preparation method thereof, ion exchange membrane containing modified polyphenyl ether, preparation method and application 2020-05-15

Literatures

PMID Publication Date Title Journal
20550218 2010-07-16 Ru-catalyzed decarbonylative addition of aliphatic aldehydes to terminal alkynes Organic letters
19707684 2009-09-21 TTMPP: An efficient organocatalyst in the ring-opening of aziridines with silylated nucleophiles Organic & biomolecular chemistry
19783929 2009-09-02 Tris(2,4,6-trimethoxyphenyl)phosphine (TTMPP): efficient catalysts for the cyanosilylation and cyanocarbonation of aldehydes and ketones Molecules (Basel, Switzerland)
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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