Tris(4-chlorophenyl)phosphine

Inquiry

Molecular Formula:

C18H12Cl3P

Molecular Weight:

365.62

CAS Number:

1159-54-2

Catalog Number:

1159-54-2

Product Information

Molecular Formula:

C18H12Cl3P

Molecular Weight:

365.62

Description

Catalyst for: Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydes; Solvent-free Heck reactions. Cocatalyst in: Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagents; Rhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenes; Rhodium-catalyzed hydrogenation reactions; Platinum-catalyzed allylation reactions.

Synonyms

tris(4-chlorophenyl)phosphine; tris(4-chlorophenyl)phosphane

IUPAC Name

tris(4-chlorophenyl)phosphane

Canonical SMILES

C1=CC(=CC=C1P(C2=CC=C(C=C2)Cl)C3=CC=C(C=C3)Cl)Cl

InChI

InChI=1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H

InChI Key

IQKSLJOIKWOGIZ-UHFFFAOYSA-N

Boiling Point

427.6 °C at 760 mmHg

Melting Point

100-103 °C (lit.)

Flash Point

Not applicable

Purity

95 %

Storage

Inert atmosphere, Room Temperature

LogP

5.40500

Safety Information

Hazards

H315 - H319 - H335

Precautionary Statement

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501

Signal Word

Warning

Computed Properties

XLogP3

6.5

Hydrogen Bond Donor Count

Hydrogen Bond Acceptor Count

Rotatable Bond Count

Exact Mass

363.974220 g/mol

Monoisotopic Mass

363.974220 g/mol

Topological Polar Surface Area

0Å²

Heavy Atom Count

Formal Charge

Complexity

275

Isotope Atom Count

Defined Atom Stereocenter Count

Undefined Atom Stereocenter Count

Defined Bond Stereocenter Count

Undefined Bond Stereocenter Count

Covalently-Bonded Unit Count

Compound Is Canonicalized

Yes

Patents

Publication Number	Title	Priority Date
CN-113698431-A	Synthesis method of phosphine (III) compound	2021-09-27
CN-112898247-A	Synthetic method of furan acetate compound	2021-03-09
CN-113149882-A	Gem-difluoroolefin-pyrroline compound and preparation method and application thereof	2021-02-05
CN-112724373-A	Functional organic porous polymer and preparation method and application thereof	2020-12-10
CN-112724373-B	Functional organic porous polymer and preparation method and application thereof	2020-12-10
WO-2022025243-A1	Polycarbonate resin composition and molded item thereof	2020-07-31
CN-113946098-A	Colored curable resin composition, color filter, and display device	2020-07-16
CN-113946100-A	Colored curable resin composition, color filter, and display device	2020-07-16
JP-2022018965-A	Color curable resin composition, color filter and display device	2020-07-16
JP-2022018966-A	Color curable resin composition, color filter and display device	2020-07-16

Literatures

PMID	Publication Date	Title	Journal
22969506	2012-09-01	cis-Dichloridobis[tris-(4-chloro-phen-yl)phosphane-κP]platinum(II) acetonitrile monosolvate	Acta crystallographica. Section E, Structure reports online
21579981	2009-12-24	Bis{[μ-bis-(diphenyl-arsino)methane-1:2κAs:As']nona-carbonyl-1κC,2κC,3κC-[tris-(4-chloro-phen-yl)phosphine-3κP]-triangulo-triruthenium(0)} chloro-form monosolvate	Acta crystallographica. Section E, Structure reports online
17268644	2006-12-21	Synthesis of stable C-phosphonate analogues of Neisseria meningitidis group A capsular polysaccharide structures using modified Mitsunobu reaction conditions	Organic & biomolecular chemistry
16390116	2006-01-11	Palladium-catalyzed synthesis of 1-alkylphosphonium salts from 1-alkenes	Journal of the American Chemical Society
1153	1975-12-01	Effect of a single administration of testosterone on the immune response and lymphoid tissues in mice	Cellular immunology

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Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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The dilution calculator equation

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This equation is commonly abbreviated as: C₁V₁ = C₂V₂

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