2,2,2-Trifluoroethyl methacrylate

Product Information

Molecular Formula:
C6H7F3O2
Molecular Weight:
168.11
Description
For reduced refractive index (1.437) polymers.
Synonyms
2,2,2-trifluoroethyl 2-methylprop-2-enoate
IUPAC Name
2,2,2-trifluoroethyl 2-methylprop-2-enoate
Canonical SMILES
CC(=C)C(=O)OCC(F)(F)F
InChI
InChI=1S/C6H7F3O2/c1-4(2)5(10)11-3-6(7,8)9/h1,3H2,2H3
InChI Key
QTKPMCIBUROOGY-UHFFFAOYSA-N
Boiling Point
59 ℃ (100 mmHg)
Flash Point
25 ℃
Purity
95 %
Density
1.181 g/cm3
Appearance
Clear colorless liquid
Application
TFEMA can be used in the preparation of poly(TFEMA), which can be used in the development of acrylic protective coatings.
Storage
Keep Cold
Refractive Index
n20/D 1.361
Stability
May undergo autopolymerization.
LogP
1.66800

Safety Information

Hazards
H226:
Flammable liquid and vapour.
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Precautionary Statement
P210, P233, P240, P241, P242, P243, P261, P264, P270, P271, P280, P301+P310, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word
Danger

Computed Properties

XLogP3
2.7
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
5
Rotatable Bond Count
3
Exact Mass
168.03981395 g/mol
Monoisotopic Mass
168.03981395 g/mol
Topological Polar Surface Area
26.3Ų
Heavy Atom Count
11
Formal Charge
0
Complexity
171
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114185246-A High-precision photoresist composition and direct writing system thereof 2022-02-17
CN-114133783-A Polymer putty, putty coating, preparation method, putty coating and application 2021-12-30
CN-114181366-A Modified acrylic polyol composition 2021-12-30
CN-114181340-A Modified styrene-maleic anhydride resin and preparation method and application thereof 2021-12-24
CN-114085558-A Staged photocuring coating, heat transfer film, decorative device and preparation method 2021-12-22
CN-114133532-A Fluorine-containing polyacrylate modified polyurethane elastomer and preparation method thereof 2021-12-16
CN-114149548-A Flame-retardant acrylic resin and solvent-type thermal foaming inkjet ink prepared from same 2021-12-15
CN-113980194-A Organic silicon modified hydroxyl epoxy acrylic resin, UV ink and preparation method thereof 2021-12-13
CN-113999574-A Fluorine-containing anticorrosive material and preparation method thereof 2021-12-09
CN-113999354-A Amphiphilic block polymer nanoparticles with different morphologies and preparation method and application thereof 2021-12-07

Literatures

PMID Publication Date Title Journal
22551478 2012-07-15 Hierarchical dual-sized film surface morphologies self-generated from fluorinated binary latex blends boost hydrophobicity and lipophobicity Journal of colloid and interface science
22204970 2012-03-01 Synthesis and self-assembly of amphiphilic gradient copolymer via RAFT emulsifier-free emulsion polymerization Journal of colloid and interface science
20825194 2010-10-05 Modification of surface wettability through adsorption of partly fluorinated statistical and block polyelectrolytes from aqueous medium Langmuir : the ACS journal of surfaces and colloids
20827030 2010-10-01 Kinetic polymerization behavior of fluorinated monomers for dental use Dental materials journal
20121228 2010-02-23 Direct patterning of intrinsically electron beam sensitive polymer brushes ACS nano
19822997 2009-09-01 Bonding durability against water of a fluorine-containing resin for precious metal alloys Dental materials journal
20355827 2009-09-01 Development of a directly patterned low-surface-energy polymer brush in supercritical carbon dioxide ACS applied materials & interfaces
20356016 2009-04-01 Copolymer-based progressive addition lens with graded index designed for astigmatism and distortion correction ACS applied materials & interfaces
19156765 2009-02-01 CEC with new monolithic stationary phase based on a fluorinated monomer, trifluoroethyl methacrylate Electrophoresis
19009087 2008-11-30 Supported ATRP of fluorinated methacrylates in supercritical carbon dioxide: preparation of scCO2 soluble polymers with low catalytic residues Chemical communications (Cambridge, England)
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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