2-(2-Bromoisobutyryloxy)ethyl methacrylate

Product Information

Molecular Formula:
C10H15BrO4
Molecular Weight:
279.13
Description
Atom Transfer Radical Polymerization (ATRP) initiator with a methacrylate functionality for branched polymerization, orthogonal polymerization, or other functionalization.
Synonyms
2-Methacryloxyethyl 2'-bromoisobutyrate,2-Methylacrylic acid 2-(2-bromo-2-methylpropionyloxy) ethyl ester,BIEM
IUPAC Name
2-(2-methylprop-2-enoyloxy)ethyl 2-bromo-2-methylpropanoate
Canonical SMILES
CC(=C)C(=O)OCCOC(=O)C(C)(C)Br
InChI
InChI=1S/C10H15BrO4/c1-7(2)8(12)14-5-6-15-9(13)10(3,4)11/h1,5-6H2,2-4H3
InChI Key
QXDYJUSFCUKOQD-UHFFFAOYSA-N
Boiling Point
162-164 °C(lit.)
Flash Point
>230 °F
Purity
95%
Density
1.303 g/mL at 25 °C
Appearance
powder
Storage
2-8°C
Refractive Index
n20/D 1.471

Safety Information

Hazards
H302

Computed Properties

XLogP3
2.4
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
7
Exact Mass
278.01537 g/mol
Monoisotopic Mass
278.01537 g/mol
Topological Polar Surface Area
52.6Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
271
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-113667066-A Brush-like microgel water lubricating additive and preparation method and application thereof 2021-09-17
CN-112871147-A Preparation method of chromatography medium for removing polymers in monoclonal antibody 2020-12-30
JP-2022041530-A Method for manufacturing grafted fine particles 2020-09-01
EP-3916029-A1 Novel methacrylate copolymer and compositions comprising it 2020-05-28
WO-2021239787-A1 Novel methacrylate copolymer and compositions comprising it 2020-05-28
WO-2021199748-A1 Composition, film, and optical sensor 2020-03-30
TW-202136364-A Composition, film and light sensor 2020-03-30
WO-2021180943-A1 Compositions improving poxvirus stability 2020-03-12
JP-2021123712-A Compositions, hardened films, laminates, ships, underwater structures, medical devices, and microchannel chips 2020-01-31
AU-2020397432-A1 Hydrogel 2019-12-02

Literatures

PMID Publication Date Title Journal
21028818 2010-12-07 Pickering emulsion templated interfacial atom transfer radical polymerization for microencapsulation Langmuir : the ACS journal of surfaces and colloids
15144819 2004-06-15 Architecture and solution properties of AB-type brush-block-brush amphiphilic copolymers via ATRP techniques Journal of colloid and interface science
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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