2-(Methacryloyloxy)ethyl acetoacetate

Product Information

Molecular Formula:
C10H14O5
Molecular Weight:
214.22
Description
2-(Methacryloyloxy)ethyl acetoacetate (CAS# 21282-97-3) is a useful research chemical.
Synonyms
2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate
IUPAC Name
2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate
Canonical SMILES
CC(=C)C(=O)OCCOC(=O)CC(=O)C
InChI
InChI=1S/C10H14O5/c1-7(2)10(13)15-5-4-14-9(12)6-8(3)11/h1,4-6H2,2-3H3
InChI Key
IBDVWXAVKPRHCU-UHFFFAOYSA-N
Boiling Point
287.4 °C at 760 mmHg
Flash Point
141 °C
Purity
95 %
Density
1.122 g/cm3
Solubility
water, 2.307e+004 mg/L @ 25 °C (est)
Appearance
Yellowish clear liquid.
Refractive Index
1.456
LogP
0.62800

Safety Information

Hazards
H315:
Causes skin irritation.
H317:
May cause an allergic skin reaction.
H319:
Causes serious eye irritation.
Precautionary Statement
P261, P264, P271, P272, P273, P280, P285, P302+P352, P304+P340, P304+P341, P305+P351+P338, P312, P321, P332+P313, P333+P313, P337+P313, P342+P311, P362, P363, P403+P233, P405, and P501
Signal Word
Danger

Computed Properties

XLogP3
0.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
5
Rotatable Bond Count
8
Exact Mass
214.08412354 g/mol
Monoisotopic Mass
214.08412354 g/mol
Topological Polar Surface Area
69.7Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
280
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114106258-A Aqueous artificial plush base fabric sizing slurry and preparation method thereof 2021-12-15
CN-114149321-A Preparation method of acetoacetoxy ethyl methacrylate 2021-12-13
CN-114181084-A Method for purifying acetoacetoxy ethyl methacrylate 2021-12-13
CN-114031743-A Self-initiated micromolecule chain extender, self-initiated polyurethane acrylate prepolymer and preparation method 2021-12-10
CN-114058232-A Submerged arc welding flash rust resistant water-based acrylic acid anticorrosive primer and preparation method thereof 2021-11-29
CN-114085330-A Modified acrylic emulsion and preparation method thereof 2021-11-18
CN-113956422-A Silane modified acrylate polymer, preparation method and application thereof, acrylate polymer coating and application thereof 2021-11-12
CN-114163590-A Soft and non-sticky high-color-fastness pigment printing adhesive and preparation method thereof 2021-11-09
CN-113980168-A Preparation method of gradient core-shell acrylic emulsion for outdoor wood paint 2021-10-28
CN-113969519-A Barrier coating for food paper and paperboard, and food paper and paperboard 2021-10-13

Literatures

PMID Publication Date Title Journal
22802208 2012-08-10 Direct nanoimprint lithography of Al₂O₃ using a chelated monomer-based precursor Nanotechnology
22200326 2012-05-01 Ammonia gas-sensing characteristics of fluorescence-based poly(2-(acetoacetoxy)ethyl methacrylate) thin films Journal of colloid and interface science
22452509 2012-04-01 Multiresponsive polymer conetworks capable of responding to changes in pH, temperature, and magnetic field: synthesis, characterization, and evaluation of their ability for controlled uptake and release of solutes ACS applied materials & interfaces
19627141 2009-09-14 Superparamagnetic hybrid micelles, based on iron oxide nanoparticles and well-defined diblock copolymers possessing beta-ketoester functionalities Biomacromolecules
19274710 2009-08-01 Synthesis and characterization of a novel in situ forming gel based on hydrogel dispersions Journal of biomedical materials research. Part B, Applied biomaterials
19138162 2009-01-20 Time-of-flight secondary ion mass spectrometry study of the orientation of a bifunctional diblock copolymer attached to a solid substrate Langmuir : the ACS journal of surfaces and colloids
18665640 2008-09-01 Self-cross-linking polyelectrolyte complexes for therapeutic cell encapsulation Biomacromolecules
17218002 2007-11-01 Dendritic copolymers and particulate filler composites for dental applications: degree of conversion and thermal properties Dental materials : official publication of the Academy of Dental Materials
17096549 2006-11-01 Synthesis of soluble phosphate polymers by RAFT and their in vitro mineralization Biomacromolecules
16380160 2006-09-01 Analysis of residual monomers in dendritic methacrylate copolymers and composites by HPLC and headspace-GC/MS Dental materials : official publication of the Academy of Dental Materials
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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