tert-Butyl methacrylate

Product Information

Molecular Formula:
C8H14O2
Molecular Weight:
142.20
Description
tert-Butyl methacrylate (CAS# 585-07-9) is a useful research chemical.
Synonyms
tert-butyl 2-methylprop-2-enoate
IUPAC Name
tert-butyl 2-methylprop-2-enoate
Canonical SMILES
CC(=C)C(=O)OC(C)(C)C
InChI
InChI=1S/C8H14O2/c1-6(2)7(9)10-8(3,4)5/h1H2,2-5H3
InChI Key
SJMYWORNLPSJQO-UHFFFAOYSA-N
Boiling Point
132 ℃
Melting Point
-60 ℃
Flash Point
30 ℃
Purity
95 %
Density
0.875 g/cm3
Solubility
water, 555.3 mg/L @ 25 °C (est)
Appearance
A colorless liquid with an ester like odor. flash point below 141°f. less dense than water and insoluble in water.
Application
tert-Butyl methacrylate (tert-BMA) can be used in the formation of homo and block copolymers by atom transfer radical polymerization (ATRP) for potential usage in coatings, biomaterials and flocculants.
Storage
Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.
Refractive Index
n20/D 1.415(lit.)
LogP
1.90420

Safety Information

Hazards
H226:
Flammable liquid and vapour.
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
H335:
May cause respiratory irritation.
Precautionary Statement
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word
Warning

Computed Properties

XLogP3
2.5
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
3
Exact Mass
142.099379685 g/mol
Monoisotopic Mass
142.099379685 g/mol
Topological Polar Surface Area
26.3Ų
Heavy Atom Count
10
Formal Charge
0
Complexity
151
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
JP-2022033265-A Adhesive sheets, repetitive bending laminated members and repetitive bending devices 2022-01-04
CN-114085311-A Method for preparing high-purity photoresist resin 2021-12-30
CN-114085559-A Antifogging and antifrosting film and preparation method thereof 2021-12-30
CN-114058199-A UV-cured super-hydrophilic anti-fog coating and preparation method and application thereof 2021-12-29
JP-2022034050-A toner 2021-12-27
CN-114149750-A Adhesive, heat-curable adhesive tape, and preparation method and use method thereof 2021-12-14
CN-113917577-A High-water-resistance and bending-resistance optical protective film, polarizer and liquid crystal display device 2021-12-13
CN-114149527-A Method for realizing controllable free radical polymerization in air atmosphere and application thereof 2021-12-10
CN-114163569-A Water-resistant surface sizing agent and preparation method and application thereof 2021-12-10
CN-114085485-A Preparation of modified collagen fiber and application thereof in rubber 2021-12-08

Literatures

PMID Publication Date Title Journal
22384926 2012-03-20 Dye-loaded porous nanocapsules immobilized in a permeable polyvinyl alcohol matrix: a versatile optical sensor platform Analytical chemistry
22755055 2012-03-01 Thermal-sensitive PBMA-b-PNIPAAm amphiphilic block copolymers brushes and their assembling micelles Journal of nanoscience and nanotechnology
22112235 2012-01-10 Formation of polyampholyte brushes via controlled radical polymerization and their assembly in solution Langmuir : the ACS journal of surfaces and colloids
22489207 2012-01-01 Separation of poly(styrene-block-t-butyl methacrylate) copolymers by various liquid chromatography techniques TheScientificWorldJournal
21919469 2011-11-01 Temperature- and pH-triggered reversible transfer of doubly responsive hairy particles between water and a hydrophobic ionic liquid Langmuir : the ACS journal of surfaces and colloids
21919505 2011-10-01 Scanning thermal lithography of tailored tert-butyl ester protected carboxylic acid functionalized (meth)acrylate polymer platforms ACS applied materials & interfaces
22110867 2011-01-01 Anisotropic nanomaterials: structure, growth, assembly, and functions Nano reviews
20232838 2010-06-15 Self-assembly of poly(4-methylstyrene)-g-poly(methacrylic acid) graft copolymer in selective solvents for grafts: scattering and molecular dynamics simulation study Langmuir : the ACS journal of surfaces and colloids
20099880 2010-06-01 Thermosensitive aqueous gels with tunable sol-gel transition temperatures from thermo- and pH-responsive hydrophilic ABA triblock copolymer Langmuir : the ACS journal of surfaces and colloids
19754064 2010-01-19 Amphoteric core-shell microgels: contraphilic two-compartment colloidal particles Langmuir : the ACS journal of surfaces and colloids
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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