4,4'-Di-tert-butyl-2,2'-dipyridyl

Product Information

Molecular Formula:
C18H24N2
Molecular Weight:
268.40
Description
2,2'-Bipyridyl has been used in the preparation of copper(II)-bipyridine-naringenin complex. It may be used in the preparation of 2,2'-bipyridyl hydrobromide.
Synonyms
4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine
IUPAC Name
4-tert-butyl-2-(4-tert-butylpyridin-2-yl)pyridine
Canonical SMILES
CC(C)(C)C1=CC(=NC=C1)C2=NC=CC(=C2)C(C)(C)C
InChI
InChI=1S/C18H24N2/c1-17(2,3)13-7-9-19-15(11-13)16-12-14(8-10-20-16)18(4,5)6/h7-12H,1-6H3
InChI Key
TXNLQUKVUJITMX-UHFFFAOYSA-N
Boiling Point
395.4 ℃ at 760 mmHg
Melting Point
159-161 ℃ (lit.)
Flash Point
228.2 °F
Purity
95 %
Density
0.977 g/cm3
Appearance
White to off-white solid
Refractive Index
n20/D 1.519
LogP
4.73860

Safety Information

Hazards
H315 H319
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning

Computed Properties

XLogP3
4.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
3
Exact Mass
268.193948774 g/mol
Monoisotopic Mass
268.193948774 g/mol
Topological Polar Surface Area
25.8Ų
Heavy Atom Count
20
Formal Charge
0
Complexity
278
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes

Patents

Publication Number Title Priority Date
CN-114032567-A Electrochemical reduction carboxylation method based on non-sacrificial anode strategy 2021-11-23
CN-114031644-A Neutral iridium complex containing nitrogen-sulfur four-membered ring coordination, and preparation method and application thereof 2021-11-22
CN-113801033-A Synthesis method of 2-aminoindan or derivatives thereof 2021-11-16
CN-113801033-B Synthesis method of 2-aminoindan or derivatives thereof 2021-11-16
CN-113999083-A Novel method for synthesizing 2, 2-difluoroethyl aromatic compound 2021-10-18
CN-113896648-A Preparation method of alpha, beta-unsaturated amide compound 2021-09-29
CN-113683646-A Monocarbon borane-containing metal platinum complex and preparation method and application thereof 2021-09-18
CN-113621131-A Polyelectrolyte material, preparation method thereof and polyelectrolyte membrane 2021-09-15
CN-113582843-A Preparation method of 5-chloro-2-fluoro-3-hydroxybenzoic acid ethyl ester 2021-09-09
CN-113698416-A Singlet oxygen carrier for inhibiting beta-amyloid protein aggregation and preparation method and application thereof 2021-08-25

Literatures

PMID Publication Date Title Journal
22684499 2012-07-21 Tailoring carrier injection efficiency to improve the carrier balance of solid-state light-emitting electrochemical cells Physical chemistry chemical physics : PCCP
22731752 2012-07-06 Iridium-catalyzed, substrate-directed C-H borylation reactions of benzylic amines Organic letters
22676275 2012-06-18 Scrutinizing low-spin Cr(II) complexes Inorganic chemistry
22591116 2012-06-04 Large improvement in the catalytic activity due to small changes in the diimine ligands: new mechanistic insight into the dirhodium(II,II) complex-based photocatalytic H2 production Inorganic chemistry
22415854 2012-04-16 Synthesis of 2- and 2,7-functionalized pyrene derivatives: an application of selective C-H borylation Chemistry (Weinheim an der Bergstrasse, Germany)
22372402 2012-03-19 An octanuclear molybdenum(VI) complex containing coordinatively bound 4,4'-di-tert-butyl-2,2'-bipyridine, [Mo8O22(OH)4(di-tBu-bipy)4]: synthesis, structure, and catalytic epoxidation of bio-derived olefins Inorganic chemistry
22258081 2012-03-07 Photophysical properties of 4,4'-di-tert-butyl-2,2'-bipyridine supported 6-membered 2,2'-diphenyl-X platinacycles (X = CH2, NMe, O) Dalton transactions (Cambridge, England : 2003)
22045119 2012-01-21 A systematic study on the synthesis, reactivity and structure of ortho-palladated aryloximes, including the first cyclopalladated aryloximato and iminoaryloxime complexes Dalton transactions (Cambridge, England : 2003)
22066656 2011-12-05 Thiocyanate linkage isomerism in a ruthenium polypyridyl complex Inorganic chemistry
22199539 2011-12-01 μ-Oxido-bis-[chlorido(4,4'-di-tert-butyl-2,2'-bipyridine-κN,N')dioxido-molybdenum(VI)] 0.2-hydrate Acta crystallographica. Section E, Structure reports online
The molarity calculator equation

Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

The dilution calculator equation

Concentration (start) × Volume (start) = Concentration (final) × Volume (final)

This equation is commonly abbreviated as: C1V1 = C2V2

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