4,4'-Dimethyl-2,2'-dipyridyl
Product Information
Molecular Formula
C12H12N2
Molecular Weight
184.24
Description
4,4'-Dimethyl-2,2'-dipyridyl (dmbipy) may be used as a ligand in the synthesis of : carbonato-bridged triangular trinuclear compounds and tetranuclear hydroxo-bridged compounds; dmbipy-copper bridged complexes, which show variation in crystal geometries, thermal and magnetic properties.
Synonyms
4-methyl-2-(4-methylpyridin-2-yl)pyridine
IUPAC Name
4-methyl-2-(4-methylpyridin-2-yl)pyridine
SMILES
CC1=CC(=NC=C1)C2=NC=CC(=C2)C
InChI
InChI=1S/C12H12N2/c1-9-3-5-13-11(7-9)12-8-10(2)4-6-14-12/h3-8H,1-2H3
InChI Key
NBPGPQJFYXNFKN-UHFFFAOYSA-N
Boiling Point
309.3 °C at 760 mmHg
Melting Point
174-176 °C
Flash Point
228.2 °F
Purity
95 %
Density
1.06 g/cm3
Appearance
Clear liquid to pale yellow liquid
Refractive Index
n20/D 1.519
LogP
2.76040
Safety Information
Hazards
H315 H319
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
2.2
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
1
Exact Mass
184.100048391 g/mol
Monoisotopic Mass
184.100048391 g/mol
Topological Polar Surface Area
25.8Ų
Heavy Atom Count
14
Formal Charge
0
Complexity
161
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113651857-A | Iridium complex for oxygen sensing and preparation method thereof | 2021-08-26 |
| CN-113637033-A | Nitrogen-containing ligand iridium complex and preparation method and application thereof | 2021-08-19 |
| CN-113501793-A | Preparation method of stable isotope labeled nitrazepam internal standard reagent | 2021-08-05 |
| CN-113549022-A | Preparation method of stable isotope labeled oxazepam internal standard reagent | 2021-08-05 |
| CN-113549078-A | Preparation method of stable isotope labeled alprazolam and estazolam internal standard reagent | 2021-08-05 |
| CN-114031566-A | Preparation method of stable isotope labeled diazepam internal standard reagent | 2021-08-05 |
| CN-113462382-A | Rare earth color light conversion material, color converter containing the same and light-emitting device | 2021-06-30 |
| CN-113372481-A | Membrane slurry for implantable glucose sensor and preparation method thereof | 2021-06-10 |
| CN-113278035-A | Electrical stimulation response type iridium (III) complex and application thereof | 2021-05-24 |
| CN-113214310-A | Preparation process of acryloxy silane oligomer | 2021-05-21 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 23027527 | 2012-11-28 | [Fe(III)(dmbpy)(CN)4]-: a new building block for designing single-chain magnets | Dalton transactions (Cambridge, England : 2003) |
| 22985442 | 2012-10-01 | Reactions of the cationic zinc thiolate model complex [Zn(Tab)4](PF6)2 with N-donor ligands and cobalt dichloride | Inorganic chemistry |
| 23125623 | 2012-10-01 | cis-Chloridobis(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')oxidovanadium(IV) chloride ethanol monosolvate monohydrate | Acta crystallographica. Section E, Structure reports online |
| 22957890 | 2012-09-27 | Modulation in selectivity and allosteric properties of small-molecule ligands for CC-chemokine receptors | Journal of medicinal chemistry |
| 22969481 | 2012-09-01 | Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(methanol-κO)indium(III) methanol monosolvate | Acta crystallographica. Section E, Structure reports online |
| 22614946 | 2012-07-26 | Novel phosphorescent hydrogels based on an Ir(III) metal complex | Macromolecular rapid communications |
| 22807705 | 2012-07-01 | Dibromido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(dimethyl sulfoxide-κO)cadmium | Acta crystallographica. Section E, Structure reports online |
| 22719328 | 2012-06-01 | Bis(acetato-κ(2)O,O')(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')copper(II) monohydrate | Acta crystallographica. Section E, Structure reports online |
| 22590089 | 2012-05-01 | catena-Poly[[[aqua-(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')zinc]-μ-3-chloro-benzene-1,2-dicaboxylato-κ(2)O(2):O(3)] [[(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')zinc]-μ-3-chloro-benzene-1,2-dicaboxylato-κ(2)O(2):O(3)]] | Acta crystallographica. Section E, Structure reports online |
| 22364649 | 2012-03-21 | Mechanisms for CO production from CO2 using reduced rhenium tricarbonyl catalysts | Journal of the American Chemical Society |
