Copper(I) bromide

Name: Copper(I) bromide
Brand: BOC Sciences
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Molecular Formula:

CuBr

Molecular Weight:

143.45

CAS Number:

7787-70-4

Catalog Number:

7787-70-4

Product Information

Molecular Formula:

CuBr

Molecular Weight:

143.45

Description

Some applications of copper bromide reported are as a :• catalyst in cross coupling reactions.• co-catalyst in Sonogashira coupling.• Lewis acid in enantioselective addition of alkynes.• reducing agent, when complexed by three molecules of pyridine initiators for the controlled polymerization of styrene, methyl acrylate and methyl methacrylate.Reductive homocoupling of α-bromo-α−chlorocarboxylates to dimethyl α,α'-dichlorosuccinate derivatives in presence of CuBr/LiOCH3 in methanol has been reported.

Synonyms

COPPER BROMIDE; COPPER(+1)BROMIDE; COPPER(I) BROMIDE; CUPROUS BROMIDE; copperbromide(cubr); coppermonobromide; Copperbromideoffwhitepowder; Cupper(Ⅰ) bromide

IUPAC Name

bromocopper

Canonical SMILES

[Cu]Br

InChI

InChI=1S/BrH.Cu/h1H/q+1/p-1

InChI Key

NKNDPYCGAZPOFS-UHFFFAOYSA-M

Boiling Point

1345°C

Melting Point

504°C

Flash Point

Not applicable

Purity

95%

Density

4.71

Solubility

Slightly sol in cold water

Appearance

White powder or crystal. Turns green to dark blue on exposure to sunlight. Sinks and mixes slowly with water.

Application

Used as a polymerization catalyst.

Storage

Store in a cool, dry place. Store in a tightly closed container.

Refractive Index

2.09

Stability

Stable, but may be air or light sensitive. Incompatible with alkali metals, strong oxidizing agents.

LogP

0.84310

Vapor Pressure

1 MM HG at 572 °C

Decomposition

WHEN STRONGLY HEATED, THEY EMIT HIGHLY TOXIC FUMES OF /HYDROGEN BROMIDE. /BROMIDES/

Computed Properties

Hydrogen Bond Donor Count

Hydrogen Bond Acceptor Count

Rotatable Bond Count

Exact Mass

141.84793 g/mol

Monoisotopic Mass

141.84793 g/mol

Topological Polar Surface Area

0Å²

Heavy Atom Count

Formal Charge

Complexity

Isotope Atom Count

Defined Atom Stereocenter Count

Undefined Atom Stereocenter Count

Defined Bond Stereocenter Count

Undefined Bond Stereocenter Count

Covalently-Bonded Unit Count

Compound Is Canonicalized

Yes

Patents

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Literatures

PMID	Publication Date	Title	Journal
4615	1975-12-01	[Blood acid-base changes produced by variations of water oxygenation in the crab Carcinus maenas (author's transl)]	Journal de physiologie