1,1-Ferrocenebis(diphenylphosphine)
Product Information
Molecular Formula
C34H28FeP2
Molecular Weight
554.38
Description
Ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing.Ruthenium-Catalyzed N-Alkylation of Amines and Sulfonamides Using Borrowing Hydrogen Methodology.
Synonyms
Ferrocene-1,1'-bis-(diphenylphosphine); Bis[1-(diphenylphosphino)-2,4-cyclopentadien-1-yl]iron; DPPF; 1,1'-Bis(diphenylphosphino)ferrocene
IUPAC Name
cyclopenta-2,4-dien-1-yl(diphenyl)phosphane;iron(2+)
SMILES
C1=CC=C(C=C1)P([C-]2C=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P([C-]2C=CC=C2)C3=CC=CC=C3.[Fe+2]
InChI
InChI=1S/2C17H14P.Fe/c2*1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;/h2*1-14H;/q2*-1;+2
InChI Key
KZPYGQFFRCFCPP-UHFFFAOYSA-N
Boiling Point
363.8 °C at 760 mmHg
Melting Point
181-183 °C
Flash Point
Not applicable
Purity
95 %
Appearance
Yellow to orange powder
Storage
2-8 °C
