2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl

DavePhos may be used as a ligand in the following reactions: Palladium catalyzed sp3 arylation of 2-substituted-N-iminopyridinium ylides with different aryl chlorides to yield functionalized pyridines; Preparation of functionalized benzylic sulfones via palladium-catalyzed Negishi cross-coupling between alkyl sulfones and aryl halides; C-C Coupling of 3-haloquinolines with aryl sulfinates via palladium-catalyzed desulfitative arylation to form the corresponding biaryl compounds. Ligand used in a Pd-catalyzed Suzuki aryl-aryl coupling leading to benzodioxepines. Useful ligand for Pd-catalyzed C-N bond formation; amination of aryl halides containing hydroxyl, amide, or enolizable ketones.

2-(2-dicyclohexylphosphinophenyl)-N,N-dimethylaniline; 2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethylaniline

2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethylaniline

CN(C)C1=CC=CC=C1C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4

InChI=1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3

ZEMZPXWZVTUONV-UHFFFAOYSA-N

539.6 °C at 760 mmHg

121-124 °C (lit.)

Not applicable

97 %

7.19220

P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501

Warning