2-Phenyl-2-propyl benzodithioate
Product Information
Molecular Formula
C16H16S2
Molecular Weight
272.43
Description
RAFT agent for controlled radical polymerization; especially suited for the polymerization of methacrylates/methacrylamides, and to a lesser extent acrylates/acrylamides and styrenes; Chain Transfer Agent (CTA)
Synonyms
2-Phenylpro-2-yl dithiobenzoate, Benzenecarbodithioic acid 1-methyl-1phenylethyl ester, Cumyl dithiobenzoate
IUPAC Name
2-phenylpropan-2-yl benzenecarbodithioate
SMILES
CC(C)(C1=CC=CC=C1)SC(=S)C2=CC=CC=C2
InChI
InChI=1S/C16H16S2/c1-16(2,14-11-7-4-8-12-14)18-15(17)13-9-5-3-6-10-13/h3-12H,1-2H3
InChI Key
KOBJYYDWSKDEGY-UHFFFAOYSA-N
Boiling Point
275.2-284.4 °C
Melting Point
35.0 to 39.0 °C
Flash Point
219.2 °F
Purity
min. 97%
Density
1.125 g/mL at 25 °C
Appearance
Orange to Brown to Dark red powder to crystal
Storage
0-10°C
Refractive Index
n20/D 1.6288
Safety Information
Hazards
H413:
May cause long-lasting harmful effects to aquatic life.
May cause long-lasting harmful effects to aquatic life.
Precautionary Statement
P273:
Avoid release to the environment.
P501:
Dispose of contents/container in accordance with local/regional/national/international regulations.
Avoid release to the environment.
P501:
Dispose of contents/container in accordance with local/regional/national/international regulations.
Computed Properties
XLogP3
5
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
4
Exact Mass
272.06934286 g/mol
Monoisotopic Mass
272.06934286 g/mol
Topological Polar Surface Area
57.4Ų
Heavy Atom Count
18
Formal Charge
0
Complexity
271
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114106516-A | Epoxy resin composition, prepreg, laminated board and printed wiring board | 2021-12-31 |
| CN-114106519-A | Modified epoxy resin matrix material for wide temperature range and preparation method and application thereof | 2021-12-09 |
| CN-114015062-A | Preparation method of photoresponse type polydopamine-coated cellulose nanocrystal | 2021-11-15 |
| JP-2022041178-A | Coated particles and their manufacturing method | 2020-08-31 |
| JP-2022039817-A | Photoresponsive polymers, photoresponsive adhesives, toners, and image forming methods | 2020-08-28 |
| US-2022066345-A1 | Photoresponsive polymer, photoresponsive adhesive, toner, and image forming method | 2020-08-28 |
| WO-2022034880-A1 | Cell culture system, cell culture method, and culture medium additive | 2020-08-12 |
| JP-2022031010-A | Photoresponsive polymer | 2020-08-07 |
| US-2022043366-A1 | Photoresponsive polymer | 2020-08-07 |
| CN-113881001-A | Block copolymer and process for producing the same | 2020-07-02 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 18652466 | 2008-08-20 | Controlled cyclopolymerization through quantitative 19-membered ring formation | Journal of the American Chemical Society |
| 17599628 | 2007-10-08 | Well-defined polymers with activated ester and protected aldehyde side chains for bio-functionalization | Journal of controlled release : official journal of the Controlled Release Society |
| 16602738 | 2006-04-01 | Well-defined lactose-containing polymer grafted onto silica particles | Biomacromolecules |
| 15571417 | 2004-12-08 | Consistent experimental and theoretical evidence for long-lived intermediate radicals in living free radical polymerization | Journal of the American Chemical Society |
| 12783552 | 2003-06-11 | Stereoblock copolymers and tacticity control in controlled/living radical polymerization | Journal of the American Chemical Society |
| 12568604 | 2003-02-12 | Ab initio evidence for slow fragmentation in RAFT polymerization | Journal of the American Chemical Society |
