DIALLYL CARBONATE
Product Information
Molecular Formula
C7H10O3
Molecular Weight
142.15
Description
Transesterification of diallyl carbonate with glycerol in the presence of a catalyst (Pd/PPh3), generates glycerol carbonate.
Synonyms
Allyl carbonate; Carbonic acid, di-2-propenyl ester; Carbonic acid, diallyl ester; carbonicacid,di-2-propenylester; DIALLYL CARBONATE; Carbonic acid diallyl
IUPAC Name
bis(prop-2-enyl) carbonate
SMILES
C=CCOC(=O)OCC=C
InChI
InChI=1S/C7H10O3/c1-3-5-9-7(8)10-6-4-2/h3-4H,1-2,5-6H2
InChI Key
JKJWYKGYGWOAHT-UHFFFAOYSA-N
Boiling Point
172.3°C at 760mmHg
Flash Point
138.2 °CF - closed cup
Purity
95%
Density
0.991 g/mL at 25 °C(lit.)
Storage
2-8°C
Refractive Index
n20/D 1.428 (lit.)
Safety Information
Hazards
H226 - H315 - H319 - H335
Precautionary Statement
P210 - P302 + P352 - P305 + P351 + P338
Computed Properties
XLogP3
1.8
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
6
Exact Mass
142.062994177 g/mol
Monoisotopic Mass
142.062994177 g/mol
Topological Polar Surface Area
35.5Ų
Heavy Atom Count
10
Formal Charge
0
Complexity
115
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113683492-A | Preparation method of 3-phenoxybromopropane or analogue thereof | 2021-08-25 |
| KR-102360338-B1 | Biodegradable capsule with improved heat resistance, manufacturing method thereof and sealing paper for biodegradable capsule | 2021-06-01 |
| CN-113248646-A | Medium-refractive index m-benzene resin monomer and preparation method thereof | 2021-04-30 |
| CN-113161621-A | Preparation method of lithium ion battery | 2021-03-10 |
| CN-214957015-U | Lithium ion battery preparation system | 2021-03-10 |
| CN-112898461-A | Scratch-resistant lens and production process thereof | 2021-01-22 |
| CN-214041750-U | Radiation dose measuring device based on thermoluminescence | 2020-12-15 |
| CN-112680148-A | Binder, preparation method of binder, electrode plate and secondary battery | 2020-12-11 |
| CN-112409587-A | Method for preparing polycarbonate photoinitiator and coating | 2020-11-23 |
| DE-102020124036-A1 | Stabilizer system containing sulfide for thiol-ene and thiol-yne compositions | 2020-09-15 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22266740 | 2012-02-27 | Pd-catalyzed reaction of allyl carbonate with polyols: the role of CO2 in transesterification versus etherification of glycerol | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 21714524 | 2011-08-17 | Contemporaneous dual catalysis: chemoselective cross-coupling of catalytic vanadium-allenoate and π-allylpalladium intermediates | Journal of the American Chemical Society |
| 21578402 | 2009-10-23 | Diallyl 5-[(4-hexyl-oxyphen-yl)imino-meth-yl]-m-phenyl-ene dicarbonate | Acta crystallographica. Section E, Structure reports online |
| 21582877 | 2009-06-17 | Allyl 4-hydroxy-phenyl carbonate | Acta crystallographica. Section E, Structure reports online |
| 19275160 | 2009-04-01 | Asymmetric synthesis of diamine derivatives via sequential palladium and rhodium catalysis | Journal of the American Chemical Society |
| 19284738 | 2009-03-20 | Enzymatic desymmetrization of prochiral 2-substituted-1,3-diamines: preparation of valuable nitrogenated compounds | The Journal of organic chemistry |
| 19325925 | 2009-01-01 | Synthesis, structure, electrochemistry, and cytotoxic properties of ferrocenyl ester derivatives | Metal-based drugs |
| 17880228 | 2007-10-11 | First desymmetrization of 1,3-propanediamine derivatives in organic solvent. Development of a new route for the preparation of optically active amines | Organic letters |
| 17337343 | 2007-05-01 | Preparation of cyclic 2',3'-carbamate derivatives of erythromycin macrolide antibiotics | Bioorganic & medicinal chemistry |
| 16426677 | 2006-05-01 | Examination of the effects of poly(N-vinylpyrrolidinone) hydrogels in direct and indirect contact with cells | Biomaterials |
