Diphenyliodonium hexafluorophosphate
Product Information
Molecular Formula
C12H10F6IP
Molecular Weight
426.08
Description
Cationic photoinitiator. Photoacid generator.
Synonyms
DPIHFP
IUPAC Name
diphenyliodaniumhexafluorophosphate
SMILES
F[P-](F)(F)(F)(F)F.[I+](c1ccccc1)c2ccccc2
InChI
InChI=1S/C12H10I.F6P/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-121-7(2,3,4,5)6/h1-10H/q+1-1
InChI Key
DSSRLRJACJENEU-UHFFFAOYSA-N
Melting Point
142 °C(dec.)
Purity
≥98%
Appearance
White to Almost white powder to crystal
Application
Cationic photoinitiator.
Safety Information
Hazards
H315:
Causes skin irritation.
H319:
Causes serious eye irritation.
Causes skin irritation.
H319:
Causes serious eye irritation.
Precautionary Statement
P264:
Wash thoroughly after handling.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:
IF ON SKIN:
Wash with plenty of soap and water.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P362+P364:
Take off contaminated clothing. [As modified by IV ATP].
And wash it before reuse. [Added by IV ATP].
Wash thoroughly after handling.
P280:
Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:
IF ON SKIN:
Wash with plenty of soap and water.
P332+P313:
If skin irritation occurs:
Get medical advice/attention.
P337+P313:
If eye irritation persists:
Get medical advice/attention.
P362+P364:
Take off contaminated clothing. [As modified by IV ATP].
And wash it before reuse. [Added by IV ATP].
Signal Word
Danger
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
7
Rotatable Bond Count
2
Exact Mass
425.94690 g/mol
Monoisotopic Mass
425.94690 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
20
Formal Charge
0
Complexity
179
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| JP-2022037181-A | A method for producing a chemically amplified photosensitive composition, a photosensitive dry film, and a method for producing a patterned resist film. | 2021-12-22 |
| CN-114133467-A | Unsaturated esterified monomer and ester low-bleeding polycarboxylate superplasticizer and preparation method thereof | 2021-12-16 |
| CN-113968945-A | Antibacterial polyurethane composite resin and preparation method and application thereof | 2021-12-15 |
| CN-114045020-A | Chopped fiber reinforced photosensitive resin for 3D printing and preparation method thereof | 2021-11-17 |
| CN-113831329-A | Crosslinking agent and preparation method and application thereof | 2021-11-05 |
| CN-113912772-A | Thermosensitive resin, environment-friendly thermosensitive plate and preparation method thereof | 2021-11-05 |
| CN-113942289-A | Imageable composition for photosensitive negative-working lithographic printing plate and plate making method thereof | 2021-10-26 |
| CN-113954502-A | Photosensitive negative-working lithographic printing plate precursor and method for making lithographic printing plate by using the same | 2021-10-26 |
| CN-114011453-A | In-situ photoinduction self-assembly synthesis method of high-dispersion Cu @ SBA-15 | 2021-10-26 |
| CN-113929900-A | Polyether high polymer and anti-reflection coating solution and preparation method thereof | 2021-10-15 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 33577942 | 2021-04-01 | Involvement of NADPH oxidase in patulin-induced oxidative damage and cytotoxicity in HEK293 cells | Food and chemical toxicology : an international journal published for the British Industrial Biological Research Association |
| 23083514 | 2012-12-01 | Polymerization kinetics and reactivity of alternative initiators systems for use in light-activated dental resins | Dental materials : official publication of the Academy of Dental Materials |
| 22854914 | 2012-09-18 | Base- and metal-free C-H direct arylations of naphthalene and other unbiased arenes with diaryliodonium salts | Chemical communications (Cambridge, England) |
| 22488067 | 2012-04-01 | Effect of thymol or diphenyliodonium chloride on performance, gut fermentation characteristics, and campylobacter colonization in growing swine | Journal of food protection |
| 22340895 | 2012-02-16 | Naloxone inhibits immune cell function by suppressing superoxide production through a direct interaction with gp91phox subunit of NADPH oxidase | Journal of neuroinflammation |
| 22240163 | 2012-01-12 | NADPH oxidase and reactive oxygen species contribute to alcohol-induced microglial activation and neurodegeneration | Journal of neuroinflammation |
| 22493722 | 2012-01-01 | Reactive oxygen species facilitate translocation of hormone sensitive lipase to the lipid droplet during lipolysis in human differentiated adipocytes | PloS one |
| 22722757 | 2012-01-01 | Role of reactive oxygen species in transforming growth factor beta1-induced alpha smooth-muscle actin and collagen production in nasal polyp-derived fibroblasts | International archives of allergy and immunology |
| 22768082 | 2012-01-01 | Myocardial autophagy after severe burn in rats | PloS one |
| 21848264 | 2011-09-07 | Enantioselective α-arylation of N-acyloxazolidinones with copper(II)-bisoxazoline catalysts and diaryliodonium salts | Journal of the American Chemical Society |
