poly(chlorotrifluoroethylene)
Product Information
Molecular Formula
(C2ClF3)n
Molecular Weight
116.47
Description
Chemical resistance, near-zero moisture absorption, low creep, high optical transparency, high electrical insulating capacity, non-flammable and low coefficient of thermal expansion.
Synonyms
Poly(trifluorochloroethylene); Poly(monochlorotrifluoroethylene); Chlorotrifluoroethylene homopolymer
IUPAC Name
1-chloro-1,2,2-trifluoroethene
SMILES
C(=C(F)Cl)(F)F
InChI
InChI=1S/C2ClF3/c3-1(4)2(5)6
InChI Key
UUAGAQFQZIEFAH-UHFFFAOYSA-N
Boiling Point
-18 °F at 760 mmHg
Melting Point
Tm (DSC) 210 °C (onset)
Flash Point
-27.8 °C
Purity
95%
Solubility
water, 4013 mg/L @ 25 °C (est)
Appearance
White powder or formed articles
Application
Used to make chlorotrifluoroethylene resins (Kel-F, Halar); Used in the synthesis of lubricants, plastics, elastomers, and other chemical products.
Tg
Tg (DSC) 103 °C (onset)
LogP
log Kow = 1.65 (est)
Vapor Pressure
4590.0 [mmHg]
Henry's Law Constant
0.311 atm-cu m/mol at 25 °C (est)
Decomposition
When heated to decomposition it emits toxic fumes of /fluorine/ and /chlorine.
Odor
Faint etheral odor
Safety Information
Hazards
n20/D 1.415
Handling
at 100° F (37.8 °C): 1.000 centistokes (1.950 cPs)
Computed Properties
XLogP3
1.9
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
3
Rotatable Bond Count
0
Exact Mass
115.9640622 g/mol
Monoisotopic Mass
115.9640622 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
6
Formal Charge
0
Complexity
72.9
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114085521-A | Copolymerized nylon polymer and preparation method thereof | 2021-12-20 |
| CN-114161874-A | Method for reinforcing and displaying stone colored drawing | 2021-12-10 |
| JP-2022033143-A | Manufacturing method of composite rubber molded body for pharmaceuticals | 2021-12-03 |
| CN-113955840-A | Method for removing chlorinated hydrocarbons in underground water of industrial site in enhanced mode through combination of zero-valent magnesium and chemical characteristics of underground water | 2021-11-30 |
| CN-114031744-A | Diisocyanate carbomethoxycyclohexane composition, modified composition thereof and preparation method | 2021-11-29 |
| CN-113930119-A | Water-based paint applied to aluminum-plastic plates and color steel coiled materials | 2021-11-25 |
| CN-113956593-A | Modified low-pressure variable fluororubber, preparation method thereof and rubber compound | 2021-11-23 |
| CN-114181481-A | Screening method and application for preparing multilayer PTFE composite expanded sheet material, expanded sheet and preparation method thereof | 2021-11-23 |
| CN-113929825-A | Carboxylic styrene-butadiene latex for building coating and preparation method thereof | 2021-11-19 |
| CN-114133475-A | Fluorine-containing anion and nonionic mixed polymerizable emulsifier, preparation method and application thereof in aqueous fluorocarbon resin synthesis | 2021-11-18 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22691065 | 2012-07-06 | Pd-catalyzed arylation of chlorotrifluoroethylene using arylboronic acids | Organic letters |
| 22025988 | 2011-10-01 | Combined third-harmonic generation and four-wave mixing microscopy of tissues and embryos | Biomedical optics express |
| 21655553 | 2011-07-21 | Living/controlled free radical copolymerization of chlorotrifluoroethene and butyl vinyl ether under 60Co γ-ray irradiation in the presence of S-benzyl O-ethyl dithiocarbonate | Chemical communications (Cambridge, England) |
| 21432976 | 2011-01-03 | Greatly enhanced energy density and patterned films induced by photo cross-linking of poly(vinylidene fluoride-chlorotrifluoroethylene) | Macromolecular rapid communications |
| 19668707 | 2009-01-01 | Adhesion molecule-modified biomaterials for neural tissue engineering | Frontiers in neuroengineering |
| 18665264 | 2008-07-30 | High-resolution, in vivo magnetic resonance imaging of Drosophila at 18.8 Tesla | PloS one |
| 17678406 | 2007-07-27 | Phase equilibria in high energy density PVDF-based polymers | Physical review letters |
| 17372960 | 2007-05-01 | Solid-state 19F MAS NMR study on the conformation and molecular mobility of poly(chlorotrifluoroethylene) | Magnetic resonance in chemistry : MRC |
| 16787060 | 2006-06-28 | A modular approach to ferroelectric polymers with chemically tunable curie temperatures and dielectric constants | Journal of the American Chemical Society |
| 16182853 | 2005-10-01 | Reductive dechlorination of chlorofluorocarbons and hydrochlorofluorocarbons in sewage sludge and aquifer sediment microcosms | Chemosphere |
