Potassium 6-bromopyridine-3-trifluoroborate
Product Information
Molecular Formula
C5H3BBrF3KN
Molecular Weight
263.89
Description
Organotrifluoroborate used in the preparation of azidobiphenyl derivatives via cross coupling reactionsOrganotrifluoroborates as versatile and stable boronic acid surrogates.
Synonyms
potassium (6-bromopyridin-3-yl)trifluoroborate; potassium; (6-bromopyridin-3-yl)-trifluoroboranuide; Potassium 6-bromopyridine-3-trifluoroborate; POTASSIUM (6-BROMOPYRIDIN-3-YL)TRIFLUOROBORANUIDE; potassium(6-bromopyridin-3-yl)trifluoroborate; Potassium (6-bromopyridin-3-yl)(trifluoro)borate(1-)
IUPAC Name
potassium(6-bromopyridin-3-yl)-trifluoroboranuide
SMILES
[B-](C1=CN=C(C=C1)Br)(F)(F)F.[K+]
InChI
InChI=1S/C5H3BBrF3N.K/c7-5-2-1-4(3-11-5)6(8,9)10/h1-3H/q-1+1
InChI Key
CEGFPZLGCYIRFV-UHFFFAOYSA-N
Melting Point
262-267 °C
Flash Point
Not applicable
Storage
2-8°C
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P261 - P305 + P351 + P338
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
5
Rotatable Bond Count
0
Exact Mass
262.91311 g/mol
Monoisotopic Mass
262.91311 g/mol
Topological Polar Surface Area
12.9Ų
Heavy Atom Count
12
Formal Charge
0
Complexity
145
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| JP-2016500645-A | Printing method | 2012-10-31 |
| JP-6353455-B2 | Printing method | 2012-10-31 |
| KR-102104692-B1 | Printing method | 2012-10-31 |
| EP-2914563-B1 | Printing process | 2012-10-31 |
| ES-2891096-T3 | Printing procedure | 2012-10-31 |
| KR-101303916-B1 | Potassium Stylenyltrifluoroborate Derivatives and Preparation Methods Thereof | 2011-10-20 |
| KR-20130043329-A | Potassium Stylenyltrifluoroborate Derivatives and Preparation Methods Thereof | 2011-10-20 |
| KR-101113791-B1 | Novel potassium azidoaryltrifluoroborate derivatives and preparation method thereof | 2009-09-07 |
| KR-20110026196-A | Novel potassium azidoaryltrifluoroborate derivatives and preparation method thereof | 2009-09-07 |
