Tetrakis(triphenylphosphite)nickel(0)

Inquiry

Molecular Formula:

[(C6H5O)3P]4Ni

Molecular Weight:

1303.86

CAS Number:

14221-00-2

Catalog Number:

14221-00-2

Product Information

Molecular Formula:

[(C6H5O)3P]4Ni

Molecular Weight:

1303.86

Description

Catalyst for alkene and alkyne hydrocyanation and styrenedimerization

Synonyms

Nickel tetrakis(triphenoxyphosphine),Tetrakis(triphenoxyphosphine)nickel,[(PhO)3P]4Ni

IUPAC Name

nickeltriphenyl phosphite

Canonical SMILES

C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.[Ni]

InChI

InChI=1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h4*1-15H

InChI Key

PGXCIAAANFTEKX-UHFFFAOYSA-N

Melting Point

145 °C (dec.) (lit.)

Flash Point

Not applicable

Storage

2-8°C

Safety Information

Hazards

H315 - H317 - H319 - H335 - H351

Precautionary Statement

P201 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313

Computed Properties

Hydrogen Bond Donor Count

Hydrogen Bond Acceptor Count

Rotatable Bond Count

Exact Mass

1298.238867 g/mol

Monoisotopic Mass

1298.238867 g/mol

Topological Polar Surface Area

111Å²

Heavy Atom Count

Formal Charge

Complexity

247

Isotope Atom Count

Defined Atom Stereocenter Count

Undefined Atom Stereocenter Count

Defined Bond Stereocenter Count

Undefined Bond Stereocenter Count

Covalently-Bonded Unit Count

Compound Is Canonicalized

Yes

Patents

Publication Number	Title	Priority Date
CA-3079019-A1	Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile	2017-10-10
CN-111263760-A	Process for the preparation of 6- (2-hydroxy-2-methylpropoxy) -4- (6- (6- ((6-methoxypyridin-3-yl) methyl) -3, 6-diazabicyclo [3.1.1] hept-3-yl) pyridin-3-yl) pyrazolo [1, 5-a ] pyridine-3-carbonitrile	2017-10-10
US-2019106438-A1	Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile	2017-10-10
US-10745419-B2	Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile	2017-10-10
US-2020308194-A1	Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile	2017-10-10
US-11098064-B2	Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbontrile	2017-10-10
US-2021380609-A1	Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile	2017-10-10
JP-2018188610-A	Method for producing polyarylene sulfide resin composition	2017-04-28
AU-2017316639-A1	Methods for cross coupling	2016-08-23
CA-3032734-A1	Methods for cross coupling	2016-08-23

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The dilution calculator equation

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