Tetrakis(triphenylphosphite)nickel(0)
Product Information
Molecular Formula
[(C6H5O)3P]4Ni
Molecular Weight
1303.86
Description
Catalyst for alkene and alkyne hydrocyanation and styrenedimerization
Synonyms
Nickel tetrakis(triphenoxyphosphine),Tetrakis(triphenoxyphosphine)nickel,[(PhO)3P]4Ni
IUPAC Name
nickeltriphenyl phosphite
SMILES
C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.C1=CC=C(C=C1)OP(OC2=CC=CC=C2)OC3=CC=CC=C3.[Ni]
InChI
InChI=1S/4C18H15O3P.Ni/c4*1-4-10-16(11-5-1)19-22(20-17-12-6-2-7-13-17)21-18-14-8-3-9-15-18/h4*1-15H
InChI Key
PGXCIAAANFTEKX-UHFFFAOYSA-N
Melting Point
145 °C (dec.) (lit.)
Flash Point
Not applicable
Storage
2-8°C
Safety Information
Hazards
H315 - H317 - H319 - H335 - H351
Precautionary Statement
P201 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
12
Rotatable Bond Count
24
Exact Mass
1298.238867 g/mol
Monoisotopic Mass
1298.238867 g/mol
Topological Polar Surface Area
111Ų
Heavy Atom Count
89
Formal Charge
0
Complexity
247
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
5
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CA-3079019-A1 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
| CN-111263760-A | Process for the preparation of 6- (2-hydroxy-2-methylpropoxy) -4- (6- (6- ((6-methoxypyridin-3-yl) methyl) -3, 6-diazabicyclo [3.1.1] hept-3-yl) pyridin-3-yl) pyrazolo [1, 5-a ] pyridine-3-carbonitrile | 2017-10-10 |
| US-2019106438-A1 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
| US-10745419-B2 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
| US-2020308194-A1 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
| US-11098064-B2 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbontrile | 2017-10-10 |
| US-2021380609-A1 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
| JP-2018188610-A | Method for producing polyarylene sulfide resin composition | 2017-04-28 |
| AU-2017316639-A1 | Methods for cross coupling | 2016-08-23 |
| CA-3032734-A1 | Methods for cross coupling | 2016-08-23 |
