1,5-Cyclooctadienepalladium(II) Dichloride

Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes , Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate , and methoxycarbonylation of iodobenzene.

Dichloro(1,5-cyclooctadiene)palladium(II); PdCl2(cod); 12107-56-1; 1,5-Cyclooctadienepalladium(II)Dichloride; Dichloro(1,5-cycloocatadiene)palladium(II); AC1NWBI6

(1Z,5Z)-cycloocta-1,5-dienedichloropalladium

C1CC=CCCC=C1.Cl[Pd]Cl

InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;

RRHPTXZOMDSKRS-PHFPKPIQSA-L

153.5°C at 760 mmHg

210°C (dec.)

Not applicable

95%

orange crystalline powder.

H315 - H319 - H335

P302 + P352 - P305 + P351 + P338