1,5-Cyclooctadienepalladium(II) Dichloride
Product Information
Molecular Formula
C8H12Cl2Pd
Molecular Weight
285.51
Description
Dichloro(1,5-cyclooctadiene)palladium(II) is a commonly used catalyst to protect alcohols as acetals by treating with 2-benzyloxy-1-propene; to synthesize bicyclooctanes from diethyl malonate and in alkene carbonylation. It can also be used to catalyze the Heck coupling of nonactivated vinyl phosphates with electron deficient alkenes; the synthesis of benzo[b]thiophenes from thioenols and to prepare an active catalyst for Mizoroki-Heck and Suzuki-Miyaura cross-coupling reactions.
Catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes , Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate , and methoxycarbonylation of iodobenzene.
Catalyst for C-C bond and C-N formation, used in Heck coupling of alkynes with alkenes , Suzuki cross-coupling of aryl bromides , allylic substitution of oximes with allylic acetate , and methoxycarbonylation of iodobenzene.
Synonyms
Dichloro(1,5-cyclooctadiene)palladium(II); PdCl2(cod); 12107-56-1; 1,5-Cyclooctadienepalladium(II)Dichloride; Dichloro(1,5-cycloocatadiene)palladium(II); AC1NWBI6
IUPAC Name
(1Z,5Z)-cycloocta-1,5-dienedichloropalladium
SMILES
C1CC=CCCC=C1.Cl[Pd]Cl
InChI
InChI=1S/C8H12.2ClH.Pd/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H;/q;;;+2/p-2/b2-1-,8-7-;;;
InChI Key
RRHPTXZOMDSKRS-PHFPKPIQSA-L
Boiling Point
153.5°C at 760 mmHg
Melting Point
210°C (dec.)
Flash Point
Not applicable
Purity
95%
Appearance
orange crystalline powder.
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P302 + P352 - P305 + P351 + P338
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
0
Exact Mass
283.93509 g/mol
Monoisotopic Mass
283.93509 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
11
Formal Charge
0
Complexity
75.4
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
2
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-111978278-A | Synthetic method of 2, 3-unsaturated glycoside compounds | 2020-08-18 |
| KR-20220015185-A | Manufacturing method of organic compound | 2020-07-30 |
| JP-2021187753-A | Method for producing 2,3,4,5,6-pentafluorostyrene | 2020-05-27 |
| JP-2020117517-A | Method for producing 2-amino-1-(pyridin-2-yl)ethanone compound | 2020-03-30 |
| CN-113493451-A | Near-infrared chemiluminescent emitter with aggregation-induced emission characteristics | 2020-03-18 |
| US-2021293713-A1 | Near-infrared chemiluminescence emitter with aggregation-induced emission properties | 2020-03-18 |
| CN-113185556-A | Organic electroluminescent material and device | 2020-01-29 |
| US-2021230197-A1 | Organic electroluminescent materials and devices | 2020-01-29 |
| WO-2021062035-A1 | Luminescent materials and methods thereof | 2019-09-27 |
| CN-110818630-A | Synthesis method of conjugated (E) -3-cycloalkenyl acrylate derivative | 2019-08-12 |
