2'-(Dicyclohexylphosphino)acetophenone ethylene ketal
Product Information
Molecular Formula
C22H33O2P
Molecular Weight
360.47
Description
Cocatalyst for:• Palladium-catalyzed amination reactions• Palladium/P,O-Ligand-catalyzed Suzuki cross-coupling
A P-O ligand that in combination with Pd2(dba)3 (cat. no. 328774) provides an active catalyst that effectively cross-couples a variety of arylboronic acids with aryl chlorides containing either electron-rich or electron-poor substituents.
A P-O ligand that in combination with Pd2(dba)3 (cat. no. 328774) provides an active catalyst that effectively cross-couples a variety of arylboronic acids with aryl chlorides containing either electron-rich or electron-poor substituents.
Synonyms
dicyclohexyl-[2-(2-methyl-1,3-dioxolan-2-yl)phenyl]phosphane; 221187-50-4; Dicyclohexyl(2-(2-methyl-1,3-dioxolan-2-yl)phenyl)phosphine; 2'-(Dicyclohexylphosphino)acetophenoneethyleneketal; 675709_ALDRICH; SCHEMBL6131405
IUPAC Name
dicyclohexyl-[2-(2-methyl-1,3-dioxolan-2-yl)phenyl]phosphane
SMILES
CC1(OCCO1)C2=CC=CC=C2P(C3CCCCC3)C4CCCCC4
InChI
InChI=1S/C22H33O2P/c1-22(23-16-17-24-22)20-14-8-9-15-21(20)25(18-10-4-2-5-11-18)19-12-6-3-7-13-19/h8-9,14-15,18-19H,2-7,10-13,16-17H2,1H3
InChI Key
ZQASITYRQOCACA-UHFFFAOYSA-N
Boiling Point
485.365°C at 760 mmHg
Melting Point
85-92°C
Purity
98%
Safety Information
Hazards
H413
Computed Properties
XLogP3
4.7
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
4
Exact Mass
360.22181729 g/mol
Monoisotopic Mass
360.22181729 g/mol
Topological Polar Surface Area
18.5Ų
Heavy Atom Count
25
Formal Charge
0
Complexity
390
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| WO-2021056466-A1 | Method for preparing secondary aromatic amine | 2019-09-27 |
| JP-2021024863-A | Organic compounds, light emitting devices, light emitting devices, electronic devices, and lighting devices | 2019-08-07 |
| KR-20210018142-A | Organic compound, light-emitting device, light-emitting apparatus, electronic device, and lighting device | 2019-08-07 |
| WO-2020208475-A1 | Organic compound, light-emitting device, light-emitting apparatus, electronic device, and lighting apparatus | 2019-04-12 |
| KR-20210151807-A | Organic compounds, light emitting devices, light emitting devices, electronic devices, and lighting devices | 2019-04-12 |
| WO-2020109922-A1 | Composition for light emitting devices | 2018-11-30 |
| TW-202031866-A | Composition for light emitting device | 2018-11-30 |
| KR-20210097146-A | Composition for light emitting device | 2018-11-30 |
| US-2022029111-A1 | Composition for Light-Emitting Device | 2018-11-30 |
| JP-2020184608-A | Light emitting device, light emitting device, electronic device and lighting device | 2018-10-10 |
