2-(Diphenylphosphino)benzaldehyde
Product Information
Molecular Formula
C19H15OP
Molecular Weight
290.30
Description
2-(Diphenylphosphino)benzaldehyde (CAS# 50777-76-9) is a useful research chemical.
Synonyms
2-diphenylphosphanylbenzaldehyde
IUPAC Name
2-diphenylphosphanylbenzaldehyde
SMILES
C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3C=O
InChI
InChI=1S/C19H15OP/c20-15-16-9-7-8-14-19(16)21(17-10-3-1-4-11-17)18-12-5-2-6-13-18/h1-15H
InChI Key
DRCPJRZHAJMWOU-UHFFFAOYSA-N
Boiling Point
417.444 °C at 760 mmHg
Melting Point
112-115 °C
Flash Point
Not applicable
Purity
95 %
Appearance
Yellow powder or crystals
LogP
3.25730
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P261, P264, P271, P280, P302+P352, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P403+P233, P405, and P501
Signal Word
Warning
Computed Properties
XLogP3
4.1
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
1
Rotatable Bond Count
4
Exact Mass
290.086052095 g/mol
Monoisotopic Mass
290.086052095 g/mol
Topological Polar Surface Area
17.1Ų
Heavy Atom Count
21
Formal Charge
0
Complexity
300
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114014891-A | Purine ring modified fluorescent probe and application thereof in cobalt ion detection | 2021-11-25 |
| CN-114085200-A | Method for preparing 2, 5-furandicarboxylic acid by using 2-furancarboxylic acid as raw material through one-pot method | 2021-11-15 |
| CN-114031494-A | Method for preparing carboxylic acid by catalyzing reaction of unsaturated hydrocarbon and formic acid by using catalyst containing noble metal compound | 2021-11-01 |
| CN-113651856-A | Phosphine zwitterionic complex and ligand, preparation method and application thereof | 2021-08-25 |
| CN-113398999-A | Catalyst for hydroboration reaction and preparation and application methods thereof | 2021-07-27 |
| CN-112679541-A | Preparation method and application of metal organic ternary cyclic compound | 2020-12-28 |
| CN-112608340-A | Tetradentate nitrogen phosphine ligand and preparation method and application thereof | 2020-11-25 |
| CN-111848321-A | Chiral aminated sulfoxide and preparation method thereof | 2020-06-12 |
| CN-113797977-A | Ruthenium catalyst and application thereof | 2020-06-12 |
| JP-2021161333-A | Polycarbonate resin composition and its molded product | 2020-04-02 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 22240994 | 2012-03-14 | Synthesis of the phosphino-fullerene PPh2(o-C6H4)(CH2NMeCH)C60 and its function as an η1-P or η3-P,C2 ligand | Dalton transactions (Cambridge, England : 2003) |
| 22324763 | 2012-03-14 | Intermolecular hydroacylation: high activity rhodium catalysts containing small-bite-angle diphosphine ligands | Journal of the American Chemical Society |
| 21989479 | 2011-12-14 | Aldimines generated from aza-Wittig reaction between bis(iminophosphoranes) derived from 1,1'-diazidoferrocene and aromatic or heteroaromatic aldehydes: electrochemical and optical behaviour towards metal cations | Dalton transactions (Cambridge, England : 2003) |
| 22219850 | 2011-11-01 | Chlorido{N-[2-(diphenyl-phosphan-yl)benz-yl]-1-(pyridin-2-yl)methanamine-κP}gold(I) | Acta crystallographica. Section E, Structure reports online |
| 21887831 | 2011-10-10 | Stereoselective synthesis of trisubstituted olefins by a directed allylic substitution strategy | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 21898610 | 2011-10-10 | Stereoselective and diversity-oriented synthesis of trisubstituted allylic alcohols and amines | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 21579327 | 2010-05-22 | Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl)ethanamine-κN,P}methylpalladium(II) dichloromethane hemisolvate | Acta crystallographica. Section E, Structure reports online |
| 21579222 | 2010-04-28 | Diphen-yl[2-(2-pyridylamino-meth-yl)phen-yl]phosphine oxide | Acta crystallographica. Section E, Structure reports online |
| 19719180 | 2009-08-06 | Total synthesis of (+)-bourgeanic acid utilizing o-DPPB-directed allylic substitution | Organic letters |
| 19452073 | 2009-06-07 | New hydridoirida-beta-diketones derived from 8-quinoline-carbaldehyde and o-(diphenylphosphino)benzaldehyde | Dalton transactions (Cambridge, England : 2003) |
