Acetylacetone Palladium(II) Salt
Product Information
Molecular Formula
Pd(C5H7O2)2
Molecular Weight
304.64
Description
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:• Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).• Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.• As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
Palladium(II) acetylacetonate (Pd(acac)2) was used in the following studies:• Typical high-temperature organic solution phase protocol for the preparation of monodisperse CuPd alloy nanoparticles (NPs).• Preparation of [(NHC)Pd(acac)L] (where L=Me, NHC = N-heterocyclic carbene) complexes. These complexes efficiently catalyze the Heck reaction of activated aryl bromides.• As catalyst in the decarboxylative cross-coupling of arylcarboxylic acids with aryl halides.
Synonyms
Palladium(II) 2,4-pentanedionate,Pd(acac)2
IUPAC Name
(Z)-4-hydroxypent-3-en-2-onepalladium
SMILES
CC(=O)\C=C(\C)O[Pd]O\C(C)=C/C(C)=O
InChI
InChI=1S/2C5H8O2.Pd/c2*1-4(6)3-5(2)7/h2*3,6H,1-2H3/b2*4-3-
InChI Key
BABLLCDZHABSRT-FDGPNNRMSA-N
Boiling Point
187.6°C at 760 mmHg
Melting Point
190°C
Flash Point
Not applicable
Purity
95%
Appearance
yellow powder
Storage
Store in a cool, dry place. Store in a tightly closed container.
Safety Information
Hazards
H319
Precautionary Statement
P305 + P351 + P338
Signal Word
Warning
Computed Properties
Hydrogen Bond Donor Count
2
Hydrogen Bond Acceptor Count
4
Rotatable Bond Count
2
Exact Mass
306.00834 g/mol
Monoisotopic Mass
306.00834 g/mol
Topological Polar Surface Area
74.6Ų
Heavy Atom Count
15
Formal Charge
0
Complexity
239
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
2
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
