Allylboronic Acid Pinacol Ester
Product Information
Molecular Formula
C9H17O2B
Molecular Weight
168.04
Description
Reagent used for: Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis ; Intermolecular radical additions ; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids ; Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction ; Stereoselective indium-catalyzed Hosomi-Sakurai reactions Reagent used in Preparation of; Cyclic sulfone hydroxyethylamines as BACE1 inhibitors for reduction of Amyloid β-Peptides ; Transmetalation of carbene Ru iodide with Ag carboxylates to give C-H-activated Ru carbene complexes as catalysts for Z-selective olefin metathesis.
Synonyms
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane; 4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane
IUPAC Name
4,4,5,5-tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane
SMILES
B1(OC(C(O1)(C)C)(C)C)CC=C
InChI
InChI=1S/C9H17BO2/c1-6-7-10-11-8(2,3)9(4,5)12-10/h6H,1,7H2,2-5H3
InChI Key
YMHIEPNFCBNQQU-UHFFFAOYSA-N
Boiling Point
50-53 °C / 5 mmHg (lit.)
Flash Point
114.8 °F - closed cup
Purity
97 %
Density
0.896 g/mL at 25 °C (lit.)
Storage
2-8 °C
Refractive Index
n20/D 1.4268 (lit.)
LogP
2.26460
Safety Information
Hazards
H226
Precautionary Statement
P210, P233, P240, P241, P242, P243, P261, P264, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P312, P321, P332+P313, P337+P313, P362, P370+P378, P403+P233, P403+P235, P405, and P501
Signal Word
Warning
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
2
Exact Mass
168.1321599 g/mol
Monoisotopic Mass
168.1321599 g/mol
Topological Polar Surface Area
18.5Ų
Heavy Atom Count
12
Formal Charge
0
Complexity
171
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-114094174-A | Preparation method and application of self-repairing polymer electrolyte | 2021-10-28 |
| CN-113801424-A | Thermoplastic resin composite material for notebook computer bottom shell and manufacturing method thereof | 2021-10-11 |
| CN-113788813-A | Fluorescent dye capable of emitting in all visible light bands and preparation method and application thereof | 2021-08-06 |
| CN-113896700-A | Micromolecular formaldehyde fluorescent probe and application thereof | 2021-07-02 |
| CN-113201293-A | High-temperature-resistant adhesive tape | 2021-05-26 |
| CN-113387816-A | Formaldehyde catching agent and preparation method and application thereof | 2021-04-28 |
| CN-112164824-A | Anion receptor type single-ion conductor flame-retardant gel polymer electrolyte and preparation method thereof | 2020-09-07 |
| CN-112164824-B | Anion receptor type single-ion conductor flame-retardant gel polymer electrolyte and preparation method thereof | 2020-09-07 |
| CN-111793465-A | Organic silicon modified soybean gum adhesive and preparation method thereof | 2020-08-18 |
| CN-111793465-B | Organic silicon modified soybean gum adhesive and preparation method thereof | 2020-08-18 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 20704395 | 2010-08-20 | Use of N-allylidene-1,1-diphenylethanamine as a latent acrolein synthon in the double nucleophilic addition reaction of ketene silyl (Thio)acetals and allylborolanes | Organic letters |
