Allyldiphenylphosphine
Product Information
Molecular Formula
C15H15P
Molecular Weight
226.2534
Description
• Cocatalyst in palladium catalyzed hydrocarboxylation reactions• Cocatalyst in Palladium catalyzed cross-coupling reactions• Ligand for hydroformylation catalysts• Ligand for the rhenium phosphinoborane pendant Lewis acid-assisted reductive coupling reactions• Catalyst precursor for alkene hydroboration
Synonyms
DIPHENYL-2-PROPENYLPHOSPHINE; DIPHENYLALLYLPHOSPHINE; ALLYLDIPHENYLPHOSPHINE; ALLYLDIPHENYLPHOSPHINE, TECH., 80%; 2-Propenyldiphenylphosphine; Allyldiphenylphosphine,80%,tech.; Diphenylphosphino
IUPAC Name
diphenyl(prop-2-enyl)phosphane
SMILES
C=CCP(C1=CC=CC=C1)C2=CC=CC=C2
InChI
InChI=1S/C15H15P/c1-2-13-16(14-9-5-3-6-10-14)15-11-7-4-8-12-15/h2-12H,1,13H2
InChI Key
PDDYFPPQDKRJTK-UHFFFAOYSA-N
Boiling Point
194-200 °C/15 mmHg (lit.)
Flash Point
235.4 °F - closed cup
Purity
95%
Density
1.049
Refractive Index
n20/D 1.619 (lit.)
Safety Information
Hazards
H315 - H319 - H335
Precautionary Statement
P302 + P352 - P305 + P351 + P338
Computed Properties
XLogP3
3.7
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
4
Exact Mass
226.091137476 g/mol
Monoisotopic Mass
226.091137476 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
16
Formal Charge
0
Complexity
182
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
1
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113402416-A | Preparation method of methoxylamine hydrochloride | 2021-05-29 |
| WO-2022003040-A1 | Process for treating keratin fibers using particular amino acids in high concentration | 2020-06-30 |
| JP-2021185399-A | Quantum dot-containing polymer and its manufacturing method | 2020-05-25 |
| WO-2021241071-A1 | Quantum dot-containing polymer and method for producing same | 2020-05-25 |
| CN-111518145-A | Cyanide-bridged metal organic compound with intramolecular magnetic transformation, and preparation method and application thereof | 2020-05-07 |
| CN-113402665-A | Dental photocurable composition comprising highly soluble photoacid generator | 2020-03-16 |
| CN-113402666-A | Dental photocurable composition with excellent color tone selectivity | 2020-03-16 |
| EP-3888615-A1 | Dental photocurable composition containing high soluble photoacid generator | 2020-03-16 |
| EP-3888616-A1 | Dental photocurable composition excellent in color tone selectivity | 2020-03-16 |
| WO-2021099522-A1 | Methods for coupling a ligand to a composite material | 2019-11-21 |
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 20872381 | 2010-11-22 | Imidazoliophosphines are true N-heterocyclic carbene (NHC)-phosphenium adducts | Chemistry (Weinheim an der Bergstrasse, Germany) |
| 16856202 | 2006-07-24 | Substituted allyl diphenylphosphine oxides as radical allylating agents | Angewandte Chemie (International ed. in English) |
