Bis(tri-tert-butylphosphine)palladium(0), Pd
Product Information
Molecular Formula
Pd[P(C4H9)3]2
Molecular Weight
511.05
Description
• Catalyst for Suzuki coupling on a multisubstituted sp3-carbon (eq. 1)• Catalyst for Stille coupling reaction of aryl chlorides (eq. 2)• Catalyst for Negishi coupling reaction (eq. 3)• Catalyst for Heck coupling to form tetrasubstituted olefins (eq. 4)• Catalyst for Buchwald-Hartwig amination of aryl halide (eq. 5)• Catalyst for carbonylation of aryl halides with carbamoylsilanes (eq. 6)
Catalyst for greener Heck reaction in TPGS-750-M.On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Catalyst for greener Heck reaction in TPGS-750-M.On the Way Towards Greener Transition-Metal-Catalyzed Processes as Quantified by E Factors
Synonyms
Pd(t-Bu3P)2
IUPAC Name
palladiumtritert-butylphosphane
SMILES
CC(C)(C)P(C(C)(C)C)C(C)(C)C.CC(C)(C)P(C(C)(C)C)C(C)(C)C.[Pd]
InChI
InChI=1S/2C12H27P.Pd/c2*1-10(2,3)13(11(4,5)6)12(7,8)9/h2*1-9H3
InChI Key
MXQOYLRVSVOCQT-UHFFFAOYSA-N
Boiling Point
229.4°C at 760mmHg
Melting Point
>300°C
Flash Point
94.6°C
Purity
95%
Appearance
Off white crystalline solid
Application
Introduced as an easier to handle Pd/P(t-Bu)3-based catalyst for the Negishi cross-coupling of aryl/vinyl chlorides.
A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.
Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.
Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.
Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
Cross-coupling of silanolates and halides.
Elimination/isomerization of enol triflates derived from β-ketoesters.
A versatile catalyst for the cross-coupling of aryl and vinyl chlorides.
Catalyst for the amination of aryl chlorides and bromides using aqueous hydroxide bases.
Useful catalyst for the cross-coupling of heteroaromatic carboxylic acids.
Pd-catalyzed Newnan-Kwart rearrangement of O-aryl thiocarbamates.
Cross-coupling of silanolates and halides.
Elimination/isomerization of enol triflates derived from β-ketoesters.
Storage
Freezer
LogP
9.72760
Safety Information
Hazards
P262
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
6
Exact Mass
510.27356 g/mol
Monoisotopic Mass
510.27356 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
27
Formal Charge
0
Complexity
128
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| CN-113831383-A | Preparation method of abiraterone | 2021-11-03 |
| CN-113960879-A | Hard mask composition, preparation method thereof and pattern forming method | 2021-11-02 |
| CN-113960880-A | Hard mask composition, preparation method thereof and pattern forming method | 2021-11-02 |
| CN-113880977-A | Olefin polymerization catalyst, preparation method and application | 2021-10-18 |
| CN-113582940-A | Lipid drop specific fluorescent probe and synthetic method thereof | 2021-09-07 |
| CN-113735730-A | Preparation method of acyl primary amine | 2021-09-02 |
| CN-113735774-A | Preparation method of multi-kinase inhibitor YTH-17 | 2021-08-31 |
| JP-2021165297-A | Pest control method | 2021-07-02 |
| CN-113336751-A | High-efficiency salt-induced kinase inhibitor and preparation method thereof | 2021-05-31 |
| CN-113264917-A | Anti-hepatitis B virus compound and preparation method and application thereof | 2021-05-28 |
