Bis(triphenylphosphine)dicarbonylnickel
Product Information
Molecular Formula
[(C6H5)3P]2Ni(CO)2
Molecular Weight
639.28
Description
Catalyst for:• Cyclotrimerization reactions• Cyclooligomerization reactions
Synonyms
Bis(triphenylphosphine)nickel(0)dicarbonyl,Dicarbonylbis(triphenylphosphine)nickel(0),Nickel(0)bis(triphenylphosphine) dicarbonyl
IUPAC Name
carbon monoxidenickeltriphenylphosphanium
SMILES
[C-]#[O+].[C-]#[O+].C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)[PH+](C2=CC=CC=C2)C3=CC=CC=C3.[Ni]
InChI
InChI=1S/2C18H15P.2CO.Ni/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-182*1-2/h2*1-15H/p+2
InChI Key
SLFKPACCQUVAPG-UHFFFAOYSA-P
Melting Point
206-209 °C (lit.)
Flash Point
Not applicable
Application
Used as a polymerization catalyst.
Storage
2-8°C
Safety Information
Hazards
H317 - H350
Precautionary Statement
P201 - P280 - P302 + P352 - P308 + P313
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
2
Rotatable Bond Count
6
Exact Mass
640.123096 g/mol
Monoisotopic Mass
640.123096 g/mol
Topological Polar Surface Area
2Ų
Heavy Atom Count
43
Formal Charge
2
Complexity
569
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
5
Compound Is Canonicalized
Yes
Literatures
| PMID | Publication Date | Title | Journal |
|---|---|---|---|
| 4973 | 1976-04-01 | Hyperactive children and the efficacy of psychoactive drugs as a treatment intervention | The American journal of orthopsychiatry |
