BrettPhos Pd G1

Name: BrettPhos Pd G1
Brand: BOC Sciences
Rating: 5 (1 reviews)

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Molecular Formula:

C43H63ClNO2PPd

Molecular Weight:

798.81

CAS Number:

1148148-01-9

Catalog Number:

BPM-168964

Product Information

Molecular Formula

C43H63ClNO2PPd

Molecular Weight

798.81

Description

BrettPhos Pd G1 is a well-defined Buchwald first-generation palladacycle precatalyst featuring a BrettPhos ligand and a 2-(2-aminoethyl)phenyl palladacycle core with a chloride counterion. It is a powerful precatalyst for classic cross-coupling reactions such as Suzuki-Miyaura, Buchwald-Hartwig amination, and C-N bond formation. The compound is bench-stable and soluble in most organic solvents. This precatalyst offers excellent functional group tolerance and high catalytic activity, making it a valuable tool in pharmaceutical synthesis and organic chemistry research.

Synonyms

Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II); Chloro[2-(dicyclohexylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2-aminoethyl)phenyl]palladium(II); BrettPhos Palladacycle; BrettPhos Palladacycle Gen. 1; Chloro[2-(dicyclohexylphosphino)-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl][2-(2-aminoethyl)phenyl]palladium(II)

IUPAC Name

dicyclohexyl-[3,6-dimethoxy-2-[2,4,6-tri(propan-2-yl)phenyl]phenyl]phosphane;palladium(2+);2-phenylethanamine;chloride

SMILES

CC(C)C1=CC(=C(C(=C1)C(C)C)C2=C(C=CC(=C2P(C3CCCCC3)C4CCCCC4)OC)OC)C(C)C.C1=CC=C([C-]=C1)CCN.[Cl-].[Pd+2]

InChI

InChI=1S/C35H53O2P.C8H10N.ClH.Pd/c1-23(2)26-21-29(24(3)4)33(30(22-26)25(5)6)34-31(36-7)19-20-32(37-8)35(34)38(27-15-11-9-12-16-27)28-17-13-10-14-18-28;9-7-6-8-4-2-1-3-5-8;;/h19-25,27-28H,9-18H2,1-8H3;1-4H,6-7,9H2;1H;/q;-1;;+2/p-1

InChI Key

IWMMXPNBCHCFCY-UHFFFAOYSA-M

Melting Point

198-204 °C

Purity

98%

Appearance

Off-white to light yellow powder

Storage

Store at 2-8 °C, protect from light, under nitrogen

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Mass (g) = Concentration (mol/L) × Volume (L) × Molecular Weight (g/mol)

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BrettPhos Pd G1

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