Cyclopentylzinc bromide solution
Product Information
Molecular Formula
C5H9ZnBr
Molecular Weight
214.42
Description
Cyclopentylzinc bromide is an organozinc reagent that can be used in: • The synthesis of polyfunctional indoles by reacting with various aryldiazonium salts via Fischer indole synthesis.• Negishi cross-coupling reactions with various haloarenes in presence of Pd-complex catalyst.• The preparation of aryl alkyl ketones by alkylation of aryl N-methyl-N-tosyl or N-benzyl-N-(tert-butoxycarbonyl) amide derivatives in the presence of Ni catalyst and imidazolidinylidene ligand.
Synonyms
Zinc, bromocyclopentyl-; cyclopentylzinc bromide; cyclopentylzinc(II) bromide; Cyclopentylzinc bromide, 0.50 M in THF; Cyclopentylzinc bromide 0.5 M in Tetrahydrofuran; bromo cyclopentylzinc; cyclopentylzincbromide; bromo(cyclopentyl)zinc; cyclopentyl zinc bromide; (cyclopentyl)zinc bromide; AKOS016018103; Cyclopentylzinc bromide, 0.5M in THF
IUPAC Name
bromozinc(1+)cyclopentane
SMILES
C1CC[CH-]C1.[Zn+]Br
InChI
InChI=1S/C5H9.BrH.Zn/c1-2-4-5-3-1/h1H,2-5H21H/q-1+2/p-1
InChI Key
GTJUPSNUGOBNMF-UHFFFAOYSA-M
Flash Point
1.4 °F - closed cup
Density
0.955 g/mL at 25 °C
Storage
2-8°C
Safety Information
Hazards
H225 - H261 - H302 - H315 - H319 - H335 - H351
Precautionary Statement
P210 - P231 + P232 - P280 - P370 + P378 - P402 + P404 - P403 + P235
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
1
Rotatable Bond Count
0
Exact Mass
211.91790 g/mol
Monoisotopic Mass
211.91790 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
7
Formal Charge
0
Complexity
27.3
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| US-2019225629-A1 | Method for preparing silahydrocarbons | 2016-09-27 |
| US-2015126449-A1 | (Aza)pyridopyrazolopyrimidinones and indazolopyrimidinones and their use | 2013-11-05 |
| JP-2015010093-A | Auxiliary ligands for organometallic complexes | 2013-07-01 |
| JP-2019220692-A | Ancillary ligands for organometallic complexes | 2013-07-01 |
| JP-6544892-B2 | Auxiliary ligands for organometallic complexes | 2013-07-01 |
| US-2015001472-A1 | Ancillary ligands for organometallic complexes | 2013-07-01 |
| JP-2020164536-A | Auxiliary ligand for organometallic complex | 2013-07-01 |
| JP-6718544-B2 | Ancillary ligands for organometallic complexes | 2013-07-01 |
| US-2016168096-A1 | Biaryl derivatives as gpr120 agonists | 2013-06-27 |
| US-2015252008-A1 | Flap modulators | 2013-02-04 |
