DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95%
Product Information
Molecular Formula
C13H30P.BF4
Molecular Weight
304.157
Description
• Cocatalyst for palladium-catalyzed Kumada couplings
This neopentylphosphine ligand proved to be superior to tris(tert-butyl)phosphine in palladium-catalyzed aminations of aryl bromides and chlorides.
This neopentylphosphine ligand proved to be superior to tris(tert-butyl)phosphine in palladium-catalyzed aminations of aryl bromides and chlorides.
Synonyms
DI-T-BUTYLNEOPENTYLPHONIUM TETRAFLUOROBORATE,MIN.95%; Di-t-butylneopentylphosphoniumtetrafluoroborate,min.95%; Di-t-butylneopentylphosphonium tetrafluoroborate, min. 95%
IUPAC Name
ditert-butyl(2,2-dimethylpropyl)phosphaniumtetrafluoroborate
SMILES
[B-](F)(F)(F)F.CC(C)(C)C[PH+](C(C)(C)C)C(C)(C)C
InChI
InChI=1S/C13H29P.BF4/c1-11(2,3)10-14(12(4,5)6)13(7,8)92-1(3,4)5/h10H2,1-9H3/q-1/p+1
InChI Key
UWNPUGYQGIWNRI-UHFFFAOYSA-O
Melting Point
258-262 °C
Flash Point
Not applicable
Purity
95%
Safety Information
Hazards
H302 + H312 - H315 - H319 - H335
Precautionary Statement
P280 - P301 + P312 + P330 - P302 + P352 + P312 - P305 + P351 + P338
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
5
Rotatable Bond Count
4
Exact Mass
304.2114308 g/mol
Monoisotopic Mass
304.2114308 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
19
Formal Charge
0
Complexity
178
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
2
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| WO-2020152200-A1 | Process for preparation of heteroarylketones | 2019-01-25 |
| WO-2019161010-A1 | Inhibitors of trpc6 | 2018-02-16 |
| CN-111868055-A | Inhibitors of TRPC6 | 2018-02-16 |
| EP-3752503-A1 | Inhibitors of trpc6 | 2018-02-16 |
| US-2021053935-A1 | Inhibitors of trpc6 | 2018-02-16 |
| JP-2021513966-A | Inhibitor of TRPC6 | 2018-02-16 |
| WO-2016029216-A2 | Method for producing amidine derivatives | 2014-08-22 |
| WO-2013041106-A1 | System providing controlled delivery of gaseous 11co for carbonylation reactions in the preparation of radiopharmaceuticals for pet imaging | 2011-09-20 |
| AU-2012302599-A1 | Process for producing N-(hetero)arylazoles | 2011-09-02 |
| AU-2012302599-B2 | Process for producing N-(hetero)arylazoles | 2011-09-02 |
