Dichlorobis(tributylphosphine)nickel(II)
Product Information
Molecular Formula
{[CH3(CH2)3]3P}2NiCl2
Molecular Weight
534.23
Description
Catalyst for:• Wenkert arylations• Regioselective [2+2+2] cycloadditions• Polymerization reactions
Synonyms
NSC 54233
IUPAC Name
dichloronickeltributylphosphane
SMILES
CCCCP(CCCC)CCCC.CCCCP(CCCC)CCCC.Cl[Ni]Cl
InChI
InChI=1S/2C12H27P.2ClH.Ni/c2*1-4-7-10-13(11-8-5-2)12-9-6-3/h2*4-12H2,1-3H32*1H/q+2/p-2
InChI Key
KPFOFXWYYUNJOZ-UHFFFAOYSA-L
Melting Point
43-45 °C (lit.)
Flash Point
Not applicable
Storage
2-8°C
Safety Information
Hazards
H302 + H312 + H332 - H314 - H317 - H334 - H350
Precautionary Statement
P201 - P260 - P280 - P303 + P361 + P353 - P305 + P351 + P338 + P310 - P308 + P313
Computed Properties
Hydrogen Bond Donor Count
0
Hydrogen Bond Acceptor Count
0
Rotatable Bond Count
18
Exact Mass
532.243123 g/mol
Monoisotopic Mass
532.243123 g/mol
Topological Polar Surface Area
0Ų
Heavy Atom Count
29
Formal Charge
0
Complexity
74.9
Isotope Atom Count
0
Defined Atom Stereocenter Count
0
Undefined Atom Stereocenter Count
0
Defined Bond Stereocenter Count
0
Undefined Bond Stereocenter Count
0
Covalently-Bonded Unit Count
3
Compound Is Canonicalized
Yes
Patents
| Publication Number | Title | Priority Date |
|---|---|---|
| EP-3623452-A1 | Phosphorus removal and alkylate production | 2018-09-14 |
| US-2020087588-A1 | Phosphorus removal and alkylate production | 2018-09-14 |
| US-10947463-B2 | Phosphorus removal and alkylate production | 2018-09-14 |
| EP-3536678-A1 | Process for producing propylene and alkylate | 2018-03-06 |
| US-2019276378-A1 | Methods of forming propylene and alkylate | 2018-03-06 |
| EP-3536678-B1 | Process for producing propylene and alkylate | 2018-03-06 |
| US-10737992-B2 | Methods of forming propylene and alkylate | 2018-03-06 |
| CA-3079019-A1 | Process for the preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo[3.1.1]heptan-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
| CN-111263760-A | Process for the preparation of 6- (2-hydroxy-2-methylpropoxy) -4- (6- (6- ((6-methoxypyridin-3-yl) methyl) -3, 6-diazabicyclo [3.1.1] hept-3-yl) pyridin-3-yl) pyrazolo [1, 5-a ] pyridine-3-carbonitrile | 2017-10-10 |
| TW-201922757-A | Preparation of 6-(2-hydroxy-2-methylpropoxy)-4-(6-(6-((6-methoxypyridin-3-yl)methyl)-3,6-diazabicyclo) [3.1.1]Hept-3-yl)pyridin-3-yl)pyrazolo[1,5-a]pyridine-3-carbonitrile | 2017-10-10 |
